Alginates Flashcards
What are impression materials used for?
Used to produce a detailed replica of the teeth and oral tissues
What are the 3 types of elastic impression materials?
- Hydrocolloids
- Elastomers
- Non-elastic materials
Give an example of a reversible and irreversible hydrocolloid
- Reversible = Agar
- Irreversible = Alginate
What are the 3 types of elastomers?
- Silicones
- Polysulphides
- Polyethers
Name 3 non-elastic impression materials
- ZOE
- Impression plaster
- Impression compound
What makes alginates irreversible hydrocolloids?
The reactions sets by a chemical cross-linking reaction
What are alginates extracted from?
Extracted from seaweed with a hydroxide
Ie with NaOH forms sodium alginate
What happens when alginate is mixed with water?
When alginate is mixed with water, it forms a colloidal suspension in it, and then it sets by a chemical cross-linking reaction
What is a typical alginate powder composition? (6)
Include percentage composition
- Na/K alginate (12%)
- Diatomaceous earth (70%)
- CaSO4 (12%)
- Na3PO4 (2%)
- Sodium silicofluoride or Sodium fluorotitinate (4%)
- Magnesium oxide (3%)
What is the role of Diatomaceous earth in alginate powder?
Acts as a filler to strengthen alginate
What is the role of CaSO4 in alginate powder?
Cross-linking agent
What is the role of Na3PO4 in alginate powder?
Retarding agent
What is the role of Sodium silicofluoride, Sodium fluorotitinate and Magnesium oxide in alginate powder?
pH controller
In sodium alginate polymer where does cross linking occur?
At COONa
Define cross link
Chemical bonds joining two polymer chains together
What joins 2 polymer chains of alginates?
What is displaced?
- Ca
- Na in COONa is displaced
What is the function of the retarder in alginate powder?
Without retarder alginate gels immediately, so a retarder gives working time
How much cross-linking occurs when phosphate ions are present in the powder?
The cross-linking reaction is suppressed while the phosphate ions are being used up
So no cross-linking
Why are pH controllers added to alginate powders?
- When setting pH of alginate initially decreases to below pH 3.5 and rises to pH 9 on setting
- When set gel is too acidic or alkaline it will give a poor plaster/stone surface
- So pH controllers are added to decrease the pH to near neutral (~8)
- In order to make it compatible with casting materials
What feature does Chromoclone have that makes the alginate easier to use?
Powder colour changes at different pH’s
With Chromoclone what colour appears when water is added to alginate?
Purple
What colour change of chromoclone needs to occur in order to indicate the alginate is ready to be loaded in a tray?
Purple to Pink
Which colour change indicates that chromoclone in a tray can be inserted into the mouth?
Pink to light peach
What are some advantages of alginates? (2)
- Very good setting behaviour
- Cheap and reliable