Aldehydes Ketones Carboxylic Acid Flashcards
1
Q
Wacker process
A
Alkene—-> ketone
Catalyst : PdCl2 / CuCl2
2
Q
Stephen’s Reduction
A
Alkyl Cynide C =N —–SnCl2 / HCl——> aldehydes
3
Q
C = O carbonyl group hybridisation
A
Sp2
4
Q
CN —H+ —->
In acidic condition
A
The nitrile group is hydrolyzed to a carboxylic acid under acidic conditions.
5
Q
CN —LIALH4—->
A
Aryl amine -NH2
6
Q
Aldehyde + Cu(OH)2 + NaOH ——> red precipitate
Fehling soln
A
Cu2O
7
Q
Product formed
1. C = O + NH2•NH2
- C=O + NH2•OH (hydroxylamine)
A
C =N•NH2
Hydrazones
C= N-OH
Oxime
8
Q
____ can not reduce fehling soln
A
Aromatic compounds
C6H5
9
Q
Name reaction
C6H5 CH0 ——-KCN—->
Alc
A
Benzoin condensation
C6h5 —CHOH–C=O —C6H5
10
Q
Shmidth reaction
A
RCOOH + NH3 ——->R•NH2 + N2 + CO2
Hydrazoic acid
