Alcohols Phenols Thiols Ethers Flashcards

1
Q

What is the general formula of alcohols?

A

R-oh

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2
Q

What is the general formula of ethers

A

R-o-r

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3
Q

How does the increase in C number affect an alcohols water solubility?

A

It decreases it

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4
Q

How does the increase in C number affect the importance of functional group

A

Negatively

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5
Q

Explain primary secondary and tertiary alcohols

A

Primary: the Carbon attached to OH is attached to 1 or no carbon atom. Secondary: The C attached to Oh is attached to two C atoms. Tertiary: The C attached to OH is attached to three C atoms

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6
Q

What are the reactions of alcohols?

A

Dehydration, oxidation, combustion

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7
Q

How does oxidation in alcohols occur?

A

H+
Alcohol → alkene

h2o

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8
Q

What does primary alcohol get oxidized to?

A

Aldehyde

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9
Q

What does aldehyde get oxidized to?

A

Carboxylic acid

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10
Q

What does secondary alcohol get oxidized to?

A

Ketone

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11
Q

What does ketone get oxidized to?

A

It doesn’t

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12
Q

What does tertiary alcohol get oxidized to?

A

It doesn’t

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13
Q

Which is more acidic, alcohols or phenols?

A

Phenols

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14
Q

What is a phenol?

A

A phenyl with a hydroxyl group attached

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15
Q

What is the relationship between phenols enol and keto form

A

They are tautomers

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16
Q

What form is dominant at equilibrium, keto or enol? are there any exceptions?

A

keto, except for phenol where enol form is more stable

17
Q

is sulfur a nucleophile?

A

yes