Alcohols (LAB) Flashcards
What is the functional group of alcohol?
R-OH
This is toxic and is known as wood alcohol
Methanol
What is the formula of methanol?
CH3OH
It burns with blue flame and forms CO2 and water
Methanol
When methanol is oxidised, it forms:
HCHO, or formaldehyde
What are the uses of methanol?
Solvent for shellac, denaturant for ethanol
What is the color of KMnO4, or potassium permanganate?
Violet/Purple
What is the color of K2Cr2O7 or potassium dichromate?
Yellowish orange
A clear colorless liquid and an ingredient in alcolic beverages
Ethanol
Also called grain alcohol
Ethanol
Ethanol formula
CH3CH2OH
It is less toxic than methanol or ethanol; clear, colorless, bitter liquid
Isopropyl alcohol
Also known as rubbing alcohol
Isopropyl alcohol
alcohol with less than 1% water
Absolute alcohol
alcohol products adulterated with toxic and/or bad tasting additives (methanol, benzene, pyridine, castor oil, gasoline, isopropyl alcohol, and acetone), making it unsuitable for human consumption
Denatured alcohol
True or false: As the length of the hydrocarbon chain increases, the solubility in water decreases
True
Which is more soluble: Ethanol or Isopropyl Alcohol
Ethanol
Which is more soluble: tert-butyl alcohol or n-butyl alcohol
Tert-butyl alcohol
Arrange the ff in decreasing solubility in water:
A - CH3OH
B - N-butyl alcohol
C - CH3CH2OH
D - Isopropyl alcohol
E - Sec-butyl alcohol
F - Tert-butyl alcohol
A, C, F, E, D, B
Lucas reagent formula:
HCl + ZnCl2
Ethanol with lucas reagent reaction:
No reaction
Sec-butyl alcohol with lucas reagent reaction:
Cloudiness within 5min, sec-butyl chloride
Tert-butyl alcohol with lucas reagent reaction:
Immediate cloudiness
Primary alcohol when oxidised turns to:
Aldehyde, green color
Secondary alcohol when oxidised turns to:
Ketone, green color
Tertiary alcohol when oxidised turns to:
No reaction, yellow color remains
Esterification of ethanol result:
Ethylacetate, plastic balloon odor
Esterification of salicylic acid:
Methyl acetate, Oil of Wintergreen – Efficascent oil
The formula of iodoform:
CHI3
What is the regeant used in iodoform test?
I2 in Kl
What is the positive result for iodoform test?
Yellow precipitate
True or false: Tertiary alcohols give positive results in iodoform test
False, it does not give (+)
This test can distinguish ethanol from methanol
Iodoform test