Alcohols, Carboxylic Acids & Esters Flashcards

1
Q

What is a reversible reaction?

A

Where the products of the reaction can themselves react to produce the original reactants

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2
Q

What happens if a reversible reaction takes place in a closed system?

A

A state of equilibrium will be reached

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3
Q

What does equilibrium mean?

A

The amounts of reactants and products will reach a certain balance and stay there

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4
Q

What happens if you raise the temperature?

A

The endothermic reaction will increase to use up extra heat

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5
Q

What happens if you reduce the temperature?

A

Exothermic reaction will increase to give out more heat

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6
Q

What happens if you raise the pressure?

A

Encourages reaction which produces less volume

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7
Q

What happens if you lower the pressure?

A

Encourage the reaction which produces more volume

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8
Q

What doesn’t change the equilibrium position?

A

Adding a catalyst because you still end up with the same amount of product

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9
Q

What produces ammonia to make fertilisers?

A

The haber process

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10
Q

What is needed to make ammonia?

A

Nitrogen - obtained from air

Hydrogen - from crude oil or natural gases

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11
Q

What industrial conditions does the haber process need to be in?

A

Pressure - 200 atomospheres
Temperature - 450 degrees
Catalyst - iron

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12
Q

Why is the pressure set as high as possible?

A

To give the best % of yield without making the plant too expensive to build

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13
Q

What does the iron catalyst do?

A

Makes reaction go faster which gets it to the equilibrium proportions quicker and keeps costs down

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14
Q

What is an alcohols functional group?

A

OH

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15
Q

What is the formula for a alcohol?

A

Cn H 2n+1 OH

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16
Q

What are the first 3 alcohols in the homologous series?

A

Methanol
Ethanol
Propanol

17
Q

What is a homologous series?

A

A group of chemicals that react in a similar way because they have the same functional group

18
Q

What are some properties of alcohols?

A
  • flammable - produce carbon dioxide
  • first 3 all dissolve completely in water to form neutral solutions
  • react with sodium to give hydrogen and alkoxides
19
Q

Why are alcohols used as solvents in industry?

A
  • can dissolve compounds that water can not - hydrocarbons and oils
  • ethanol is the solvent for perfumes
  • ethanol - clean paint brushes
20
Q

What else can ethanol be used for?

A
  • fuels

- ferment sugar cane -renewable

21
Q

What is the functional group for carboxylic acids?

A

COOH

22
Q

How would you draw the functional group for carboxylic acids?

A
O
      //
-C 
      \
        OH
23
Q

What are the first 3 carboxylic acids?

A

Methanoic acid
Ethanoic acid
Propanoic acid –> C2H5COOH

24
Q

What do you get if you react a caboxylic acid with a carbonate?

A

Salt water and carbon dioxide
But the salt would end in anoate
Eg . Ethanoic acid + sodium carbonate –> sodium ethanoate + water + carbon dioxide

25
Q

What can ethanoic acid be used for?

A

Dissolved in water to make vinegar which can be used to preserve foods

26
Q

What can carboxylic acids be used for with long chains?

A

Soap and detergents

27
Q

What are esters functional group?

A

COO

28
Q

What does a alcohol + carboxylic acid —>?

A

Ester + water

29
Q

The alcohol forms the…?

The acid forms the…?

A

First part of the ester
The second part
Eg. Methanol + propanoic acid –>methyl propanoate + water

30
Q

What are the properties of esters?

A
  • pleasant smells - perfumes
  • flammable
  • don’t mix well with water
31
Q

What are esters used for?

A
  • perfumes
  • flavourings
  • solvents for paint ink glue
32
Q

Some esters are…?

A

Toxic in large doses