Alcohols Flashcards
what is the functional group of alcohols?
OH group
what is meant by primary, secondary or tertiary alcohol?
if the C bonded with the OH group is bonded with 1, 2 or 3 other C atoms, it is considered a primary, secondary or tertiary alcohol, respectively
by what kind of reaction can alcohols be formed from halogenoalkanes, and name the reagent?
reflux, aqueous alkali
by what kind of reaction can alcohols be formed from aldehydes, ketones or carboxylic acids?
reduction
what kind of alcohol is formed by reducing an aldehyde?
primary
what kind of alcohol is formed by reducing a ketone?
secondary
name the reagent for production of an alcohol from aldehyde/ketone
aqueous NaBH4
reagents/conditions for chlorination of alcohol+ product formed?
gaseous HCl, anhydrous ZnCl2, forms halogenoalkane (Cl)
reagents/conditions for bromination of alcohol+ product formed?
in situ, KBr, 50% H2SO4, forms halogenoalkane (Br)
reagents/conditions for iodination of alcohol+ product formed?
reflux, excess hydriodic acid, forms halogenoalkane (I)
product formed + observations of reaction with ethanoyl chloride?
ester formed, misty fumes HCl
product formed + reagent for reaction with carboxylic acid?
ester + H2O formed, concentrated H2SO4