ALCOHOL Flashcards
1
Q
KMnO4 reacts with _ to form Alcohol
A
3°carbon only
2
Q
Methane + ½O2 + _ gives CH3OH
A
(only)CH4 + ½O2 + Cu[100atm,523K] –> CH3OH
3
Q
When will a double bond(alkene) form ALCOHOL
A
-
OMDM
[markonikov-c+stability addn (h2o) OH & no rearrn of C+] -
HBO
[anti markno- not c+ stabil addn of h2o (OH) & no C+ rearr] -
Addn X2/H2O or HO-X+
[same as omdm product] -
SeO2
[allylic oxidation (next to db alkene)* oh-c-c=c*] -
DIOLS
KMnO4, OsO4–> SYN GLYCOL
mcpba, AG + ½O2/H2O –>ANTI GLYCOL -
acidic Hydrolysis- H3O+ or H+(aq)
[c+ rearrangement & add of oh]
4
Q
=O + NaBH4
A
-OH
5
Q
=O +LiAlH4
A
-OH
