Alchene - proprietati chimice Flashcards

1
Q

Deshidratarea Omogena a Alcoolilor

A

H2SO4 la 30-180 Grade C

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2
Q

Deshidratarea Eterogena a Alcoolilor

A

AL2O3, SiO2 la 300-400 grade C

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3
Q

Regula lui Zaitev

A

Produsul majoritar se obtine prin indepartarea H de la C vecin mai sarac in H.

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4
Q

Dehidrohalogenarea Derivatilor Halogenati

A

KOH in mediu alcoolic la 70-100 grade C

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5
Q

Dehidrogenarea Alcanilor

A

t>650 grade C

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6
Q

Hidrogenarea Alchinelor

A

Pd otravit cu saruri de Pb (Pd/Pb2+)

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7
Q

Cracarea Alcanilor

A

t<650 grade C

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8
Q

Aditia de H2

A

Ni,Pt,Pd la 200 grade C si 200 atm

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9
Q

Aditia de X

A

CCl4 sau CS2 sauCH2CL2

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10
Q

Aditia de HX

A

HgCl2, CCl4, FeCl3

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11
Q

Legea lui Markovnikov

A

Halogenul se duce la C mai sarac in H

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12
Q

Aditia Karasck

A

propena + HBr ==(peroxizi)=> 1-bromopropan

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13
Q

Metoda Industriala de Obtinere a Etanolului

A

etena + H2O ==(H3PO4/AL2O3; 250-300 C; 70-80 atm)==> etanol

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14
Q

Aditia H2O

A

H2SO4 concentrat la 0-25 grade C

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15
Q

Monomer Vinilic

A

H2C=CH-R

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16
Q

Substitutie Alilica

A

500 grade C

17
Q

Amonoxidarea Propenei

A

propena + 3/2O2 + NH3 ==(Pt, 1000 C)==> CH2=CH-C_=N + 3H2O

18
Q

Oxidarea Blanda

A

KMnO4 in mediu neutru sau slab bazic

19
Q

Reducerea KMnO4 in H2O

A

2KMnO4 + H2O ==> 2KOH + 2MnO2 + 3[O]

20
Q

Oxidarea Energica

A

KMnO4 sau K2Cr2O7 in H2SO4

21
Q

Reducerea KMnO4 in H2SO4

A

2KMnO4 + 3 H2SO4 ==> K2SO4 + 2MnSO4 + 3H2O + 5[O]

22
Q

Reducerea K2Cr2O7 in H2SO4

A

K2Cr2O7 + 4H2SO4 ==> K2SO4 + Cr2(SO4)3 + 4H2O + 3[O]

23
Q

CH2= (prin oxidare degradativa)

A

CO2 + H2O

24
Q

R-CH= (prin oxidare degradativa)

A

R- C=O-OH (acid carboxilic)

25
Q

R-C= -R’ (prin oxidare degradativa)

A

R-C=O-R’ (cetona)