Air and Solid Waste Flashcards
Principal Organic Hazardous Constituents (POHC) is regulated under?
RCRA (Resource Conservation and Recovery Act)
Regulations under RCRA impose restrictions on emissions from hazardous waste incinerators. The regulations define:
POHC present in the waste feed and establish performance standards for their destruction and removal in the incineration process.
POHC performance standard is defined by a destruction removal efficiency (DRE) of:
99.99% or four nines for each POHC in the waste feed
For Dioxins and Furans - 99.9999% or six nines required
The DRE only includes the removal efficiency of the air pollution control equipment. True or false?
False. The DRE includes both the removal efficiency of the air pollution control equipment and the destruction efficiency of the incinerator.
________is heat exchanged by a thermodynamic system in which the exchange of heat changes the temperature of the system but leaves unchanged other variables of the system, such as volume or pressure.
Sensible Heat
How is the sensible heat of a thermodynamic process calculated?
It is the product of the mass flow with its specific heat capacity and the change in temperature.
What is the energy released or absorbed by a thermodynamic system during a constant-temperature process? It is calculated by mass flow times the change in enthalpy values during the phase change.
Latent Heat
What are the two forms of latent heat?
Heat of fusion - the heat that must be absorbed to melt a mole of solid.
Heat of vaporization - the heat that must be absorbed to boil a mole of a liquid.
What are condensers used for?
Pretreatment (used before other emission control processes to remove VOCs when they occur as high concentration vapors to reduce operating costs)
Condenser recovery efficiencies over 95% are possible for vapor streams containing over ______ VOCs
10,000 ppmv
Condenser recovery efficiencies fall below ____ % when vapor concentrations are near 500 ppmv.
50
What is the most common condenser?
A non-contact shell and tube surface condenser, which is essentially a heat exchanger.
First Law of Thermodynamics =
Conservation of Energy
The change in enthalpy will be _____ for exothermic reactions.
Negative
A strong acid will disociate quickly and release heat in the presence of ____
Water
What is the general equation for a complete combustion reaction?
CH4 + 2O2 -> CO2 + 2H2O
Henry’s Law is a gas law that states:
The amount of dissolved gas in liquid is proportional to its partial pressure above the liquid.
Henry’s law constant is the ____
Proportionality Factor
Chemical equilibrium is also known as _____
Dynamic Equilibrium
When the volume of an equilibrium mix of gases is reduced -
A net change will occur in the direction that produces fewer moles of gas.
A net change will occur in the direction that produces more moles of gas when -
The volume of an equilibrium mix of gases is increased.
Increasing the temperature will shift the equilibrium in the direction of the ____ reaction.
Endothermic
Decreasing the temperature will cause a shift in the direction of the _____ reaction.
Exothermic
What is the principal effect of the temperature on the equilibrium?
It changes the equilibrium constant.