AI Generated Flashcards

1
Q

What occurs when chemical reactions do not go to completion?

A

Reversibility of chemical reactions

Reversible reactions can form products that can react with each other to reform the original reactants.

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2
Q

What is the difference between static and dynamic equilibrium?

A

Static equilibrium is a static state in which the concentrations of reactants and products are constant and the rates of forward and reverse reaction are equal and zero. Dynamic equilibrium is a steady state in which the concentrations of reactants and products are constant and the rates of forward and reverse reaction are equal and non-zero.

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3
Q

What is an example of a reversible reaction?

A

N2 (g) + 3H2 (g) ⇌ 2 NH3 (g)

Nitrogen and hydrogen can react with each other to form ammonia, which can also react with itself to reform into nitrogen and hydrogen.

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4
Q

What happens in irreversible reactions?

A

Reactants convert to products and cannot revert back to reactants.

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5
Q

What is the result of heating magnesium in a combustion reaction?

A

Formation of magnesium oxide (MgO)

The reaction is: 2 Mg (s) + O2 (g) → 2 MgO (s).

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6
Q

What is formed when iron reacts with oxygen in a combustion reaction?

A

Iron(III) oxide (Fe2O3)

The reaction is: 4 Fe (s) + 3 O2 (g) → 2 Fe2O3 (s).

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7
Q

Fill in the blank: In reversible reactions, the _______ reaction and reverse reaction occur simultaneously.

A

forward

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8
Q

What happens when hydrated cobalt(II) chloride is heated?

A

It changes color from pink to sky blue

This indicates dehydration, and adding water back will return it to its original state.

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9
Q

What does the term ‘irreversibility’ refer to in chemical reactions?

A

The inability of products to reform into reactants after the reaction has occurred.

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10
Q

True or False: All chemical reactions are reversible.

A

False

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11
Q

What signifies the formation of a complex in cobalt(II) chloride?

A

The change in color when water is added

Cobalt(II) chloride hexahydrate (CoCl2·6H2O) indicates hydration.

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12
Q

What is the result of heating CoCl2 · 6H2O?

A

It removes 4 molecules of water to form CoCl2 · 2H2O and further heating removes the other 2 water molecules to form CoCl2 (s)

This reaction demonstrates the dehydration of cobalt(II) chloride hexahydrate.

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13
Q

What happens in the reverse reaction of CoCl2?

A

Adding 2 molecules of deionized water and 4 molecules turns it back into the original pink CoCl2 · 6H2O

This illustrates the reversibility of the hydration reaction.

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14
Q

Write the net ionic equation for the reaction of iron(III) nitrate and potassium thiocyanate.

A

Fe^3+ (aq) + SCN^- (aq) → FeSCN^2+ (aq)

This equation excludes spectator ions and focuses on the ions that undergo change.

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15
Q

What is the definition of a net ionic equation?

A

Equations that show only the species that undergo change, excluding ‘spectator ions’

Net ionic equations are applicable only in aqueous solutions.

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16
Q

What does true dynamic equilibrium mean?

A

Dynamic Equilibrium is a steady state in which the concentrations of reactants and products are constant and the rates of forward and reverse reactions are equal and non zero.

i.e. both the forward and reverse reaction are occurring simultaneously.

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17
Q

Fill in the blank: At equilibrium, the concentrations of substances ______.

A

remain constant

18
Q

True or False: In a dynamic equilibrium, the rates of the forward and reverse reactions are not equal.

19
Q

What is the color of the product formed from the reaction of iron(III) nitrate and potassium thiocyanate?

A

Blood-red

This color change indicates the formation of the complex ion FeSCN^2+.

20
Q

What indicates that a chemical reaction is reversible?

A

The ability to convert reactants back into products continually

This can be observed through the changes in color of cobalt(II) chloride during hydration and dehydration.

21
Q

What is the significance of ‘spectator ions’ in net ionic equations?

A

They remain unchanged during the reaction

Spectator ions do not participate in the chemical change and are excluded from the net ionic equation.

22
Q

What is a true dynamic equilibrium?

A

A state where reactants form products and products form reactants simultaneously

This equilibrium means that the reaction will never reach 100% completion.

23
Q

What occurs at the point of dynamic equilibrium in a reaction?

A

The rate at which products and reactants are being made becomes equal

This means both reactants and products are always present.

24
Q

In a dynamic equilibrium, what can be observed in a reaction involving multiple substances?

A

A mix of colors, (including pale-orange, colorless, and blood-red in the reaction of iron (III) nitrate and potassium thiocyanate)

This indicates that all three substances are always present in the reaction.

25
Define a closed system in the context of chemical reactions.
A system where no matter is transferred, only energy is exchanged ## Footnote This system contains a constant number of particles.
26
What is the difference between a closed system and an open system?
Closed systems only exchange energy, while open systems exchange both matter and energy ## Footnote Open systems allow for constant input and output of materials.
27
What do static and dynamic equilibria require?
Closed systems ## Footnote This is essential for maintaining equilibrium conditions.
28
What happens in an open system regarding concentrations of substances?
Concentrations are always changing due to the constant input and output of matter ## Footnote This prevents the formation of a steady state.
29
True or False: In a closed system, matter can be transferred in or out.
False ## Footnote Closed systems do not allow matter transfer, only energy exchange.
30
Fill in the blank: The universe is defined as _______.
system + surroundings ## Footnote This includes all matter and energy involved in a chemical reaction.
31
What is an isolated system?
A system that does not permit matter or energy to transfer.
32
Define equilibrium.
A state where concentrations of reactants and products are constant and rates of forward and reverse reactions are equal.
33
What is static equilibrium?
A static state where concentrations of reactants/products are constant and rates of forward and reverse reactions are zero.
34
What characterizes dynamic equilibrium?
Concentrations of reactants/products are constant and rates of forward and reverse reactions are non-zero.
35
What is the difference between reversible and non-reversible reactions?
Reversible reactions never reach completion, while non-reversible reactions reach completion.
36
Provide an example of a reversible reaction.
N₂(g) + 3H₂(g) ⇌ 2NH₃(g)
37
Provide an example of a non-reversible reaction.
C(graphite) → C(diamond)
38
What is the first step in modeling dynamic equilibrium?
Place 50 marbles in container A (reactants) and 50 marbles in container B (products).
39
What action is taken in the second step of modeling dynamic equilibrium?
Transfer half the marbles from A to B (forward reaction) and one quarter from B back to A (reverse reaction).
40
What is the point of repeating the marble transfer process in the dynamic equilibrium model?
To model dynamic equilibrium - constant concentrations of reactants/products and equal rates of forward and reverse reactions.
41
List some limitations of the dynamic equilibrium model.
* Does not show constant exchange of matter * Does not show collisions that occur in reality * No energy change is shown.