AI Generated Flashcards
What occurs when chemical reactions do not go to completion?
Reversibility of chemical reactions
Reversible reactions can form products that can react with each other to reform the original reactants.
What is the difference between static and dynamic equilibrium?
Static equilibrium is a static state in which the concentrations of reactants and products are constant and the rates of forward and reverse reaction are equal and zero. Dynamic equilibrium is a steady state in which the concentrations of reactants and products are constant and the rates of forward and reverse reaction are equal and non-zero.
What is an example of a reversible reaction?
N2 (g) + 3H2 (g) ⇌ 2 NH3 (g)
Nitrogen and hydrogen can react with each other to form ammonia, which can also react with itself to reform into nitrogen and hydrogen.
What happens in irreversible reactions?
Reactants convert to products and cannot revert back to reactants.
What is the result of heating magnesium in a combustion reaction?
Formation of magnesium oxide (MgO)
The reaction is: 2 Mg (s) + O2 (g) → 2 MgO (s).
What is formed when iron reacts with oxygen in a combustion reaction?
Iron(III) oxide (Fe2O3)
The reaction is: 4 Fe (s) + 3 O2 (g) → 2 Fe2O3 (s).
Fill in the blank: In reversible reactions, the _______ reaction and reverse reaction occur simultaneously.
forward
What happens when hydrated cobalt(II) chloride is heated?
It changes color from pink to sky blue
This indicates dehydration, and adding water back will return it to its original state.
What does the term ‘irreversibility’ refer to in chemical reactions?
The inability of products to reform into reactants after the reaction has occurred.
True or False: All chemical reactions are reversible.
False
What signifies the formation of a complex in cobalt(II) chloride?
The change in color when water is added
Cobalt(II) chloride hexahydrate (CoCl2·6H2O) indicates hydration.
What is the result of heating CoCl2 · 6H2O?
It removes 4 molecules of water to form CoCl2 · 2H2O and further heating removes the other 2 water molecules to form CoCl2 (s)
This reaction demonstrates the dehydration of cobalt(II) chloride hexahydrate.
What happens in the reverse reaction of CoCl2?
Adding 2 molecules of deionized water and 4 molecules turns it back into the original pink CoCl2 · 6H2O
This illustrates the reversibility of the hydration reaction.
Write the net ionic equation for the reaction of iron(III) nitrate and potassium thiocyanate.
Fe^3+ (aq) + SCN^- (aq) → FeSCN^2+ (aq)
This equation excludes spectator ions and focuses on the ions that undergo change.
What is the definition of a net ionic equation?
Equations that show only the species that undergo change, excluding ‘spectator ions’
Net ionic equations are applicable only in aqueous solutions.
What does true dynamic equilibrium mean?
Dynamic Equilibrium is a steady state in which the concentrations of reactants and products are constant and the rates of forward and reverse reactions are equal and non zero.
i.e. both the forward and reverse reaction are occurring simultaneously.
Fill in the blank: At equilibrium, the concentrations of substances ______.
remain constant
True or False: In a dynamic equilibrium, the rates of the forward and reverse reactions are not equal.
False
What is the color of the product formed from the reaction of iron(III) nitrate and potassium thiocyanate?
Blood-red
This color change indicates the formation of the complex ion FeSCN^2+.
What indicates that a chemical reaction is reversible?
The ability to convert reactants back into products continually
This can be observed through the changes in color of cobalt(II) chloride during hydration and dehydration.
What is the significance of ‘spectator ions’ in net ionic equations?
They remain unchanged during the reaction
Spectator ions do not participate in the chemical change and are excluded from the net ionic equation.
What is a true dynamic equilibrium?
A state where reactants form products and products form reactants simultaneously
This equilibrium means that the reaction will never reach 100% completion.
What occurs at the point of dynamic equilibrium in a reaction?
The rate at which products and reactants are being made becomes equal
This means both reactants and products are always present.
In a dynamic equilibrium, what can be observed in a reaction involving multiple substances?
A mix of colors, (including pale-orange, colorless, and blood-red in the reaction of iron (III) nitrate and potassium thiocyanate)
This indicates that all three substances are always present in the reaction.