Addition reactions of alkenes Flashcards
define the term addition reaction.
a reaction in which two molecules combine to form one molecule
What happens when an alkene reacts with a halogen?
the alkene becomes saturated, with the pi bond breaking to form two new sigma bonds, one with each halogen molecule.
explain why the pi bond breaks in addition reactions.
the pi bond contains a pair of shared electrons which are less under the control of the carbon atoms in the C=C bond than the tightly held electrons in the sigma bond. this does mean a double bond is stronger than a single bond, but not twice as strong. the pi bond is more easily broken to form two new single covalent bonds.
what is the test for unsaturated hydrocarbons?
bromine water is added, and turns colourless from orange.
what is a diol?
a compound containing two OH (alcohol) groups
what is hydration?
involves the addition of water or steam, as an H and OH on the carbon atoms which previously had a double C=C bond
what is halogenation?
involves the addition of a halogen
what is hydrogenation?
involves the addition of hydrogen
why can’t hydrogen halides be used as a test for double C=C bonds?
Because both reactants (hydrogen halide and alkene) and the products (halogenoalkane) and colourless