ACS final Flashcards

1
Q

Which pH value indicates the most basic solution?

7,8,3,11,5

A

11- over 7=basic, under 7=acidic

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2
Q

To be nonpolar a molecule must have either:

A

nonpolar bonds, as in H2 or F2, or slightly polar bonds and a symmetric shape as in CH4.

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3
Q

The volume of a given mass of an ideal gas at constant pressure is

A

directly proportional to the Kelvin temperature.

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4
Q

Under which conditions does a real gas behave most nearly like an ideal gas?

A

low pressure and high temperature

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5
Q

The atomic number of any atom is equal to the number of:

A

protons in the atom, only

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6
Q

How many calories are equivalent to 35 kilocalories?

A

35,000 calories

Kilo means 103 which is 1,000. Therefore, 35 kilocalories is equal to 35,000 calories.

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7
Q

Hydrogen usually has a +1 oxidation number. However, it can have a -1 oxidation number when it behaves as the nonmetal. This occurs only when it joins with ________, which are less electronegative than hydrogen.

A

Group 1 metals

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8
Q

Which change occurs when an Sn2+ ion is oxidized?

A

Oxidation means loss of electrons. When an Sn2+ ion is oxidized, it must lose electrons, and its electric charge must become more positive as a result.

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9
Q

The size of the atoms in one group _____ as you go down that group in the periodic table.

A

increases

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10
Q

Lewis Base is

A

electron pair donor

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11
Q

Bronsted Lowry acid is

A

a proton donor

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12
Q

Given H3O+ use what equation to solve for pH

A

-log(H3O+)

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13
Q

A solid is poor conductor of heat and electricity. and has low mp, this is classified as

A

molecular

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14
Q

the mp of an impure solid is generally ____ than that of a pure solid

A

lower

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15
Q

what factor effects the vapor pressure of a liquid

A

temp

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16
Q

a gas or vapor may be liquified only at temp

A

at or below the critical temp

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17
Q

density formula

A

d=m/V

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18
Q

m1v1=

A

m2v2

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19
Q

PV=

A

nRT

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20
Q

q=mxsx?

A

delta T

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21
Q

Molarity=

A

mol/L

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22
Q

molality

A

mol solute/kg solvent

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23
Q

molarity also =deltaTf/?

A

Kf

24
Q

P1V!/T1=

A

P2V2/T2

25
Q

qsystem=

A

-qsurroundings

26
Q

DeltaGo=deltaHo+?

A

TdeltaSo

27
Q

DeltaGo=-RT?

A

lnK

28
Q

deltaGo=-nF?

A

Eocell

29
Q

Eocell=.592/n?

A

logK

30
Q

t1/2=

A

.693/k

31
Q

Rate law 1st order reactions lnNt/No=

A

-kt

32
Q

deltaTf=

A

Kfc

33
Q

DeltaTb=

A

Kbc

34
Q

H3O+(OH-)=Kw=

A

1x10^-14

35
Q

Ph=-log?

A

H3O+

36
Q

pOH=-log

A

OH-

37
Q

pH=pKa+log?

A

base/acid

38
Q

pKa

A

-logKa

39
Q

KaKb=

A

Kw

40
Q

Rate=

A

kN

41
Q

DeltaE=

A

(deltam)c^2

42
Q

KP=Kc?

A

RT^delta n

43
Q

pie=

A

MRT conc of solutionxRxT

44
Q

deltaG=deltaGo+

A

RTlnQ

45
Q

Ea=R(?)

A

(ln(k1/k2)/1/t2-1/t1)

46
Q

Raolts Psolution=

A

XsolventPoSolvent

47
Q

Lewis Acid

A

electron pair acceptor

48
Q

Lewis Base

A

electron pair donor

49
Q

number of nearest neighbors in a body centered cubic lattice?

A

8

50
Q

number of nearest neighbors in a face centered?

A

13

51
Q

number of nearest neighbors in a primitive or simple?

A

7

52
Q

heat=mx?x?

A

specific heat x change in temp

53
Q

vaporized=____ and condensed=____

A

endo,exo

54
Q

in a bomb calorimeter, reactions are carried out at constant

A

volume

55
Q

more negative enthalpy=more

A

exothermic

56
Q

activated complex–>products is always

A

exothermic