Acids, Bases and Salts Flashcards
What is an acid?
An acid is a compound which when dissolved in water yields hydronium ion [H3O+] as the only positively charged ions
Give the equation representing addition of an acid to water, and formation of hydronium cation
HCl (aq) ⇌ H+ + Cl-; H+ + H2O ⇌ H3O+
HCl + H2O ⇌ H3O+ + Cl-
What is a base?
A base is a compound which reacts with hydronium ions of an acid to give salt and water only
Give an equation representing reaction of a base with a hydronium ion of an acid
CuO + 2HCl -> CuCl2 + H2O
Cu(OH)2 + H2SO4 -> CuSO4 + 2H2O
What is an alkali?
An alkali is a compound which when dissolved in water yields hydroxyl ions [OH-] as the only negatively charges ions
Give an equation representing the reaction of an alkali with water
NaOH [aq] ⇌ Na+ + OH- [Hydroxyl or hydroxide ion]
Is an alkali a base or an acid?
An alkali is a soluble base (in water)
Give examples of soluble bases (alkalis)
KOH, NaOH [strong alkalis], Ca (OH)2, NH4OH [weak alkalis], LiOH
Give an example of a strong alkali
NaOH
Give an example of a weak alkali
NH4OH
What are organic acids?
Acids derived from plants
Give examples of organic acids
Citric, oxalic, tartaric, acetic acid
What is an inorganic acid?
Acids derived from minerals [mineral acids]
Give examples of inorganic acids
HCl, H2SO4, HNO3
Name two acids on basis of source of acids
- Organic
2. Inorganic
Name two acids on basis of molecular composition
- Hydracids
2. Oxyacids
What are hydracids?
Acids containing hydrogen and a non-metallic element other than oxygen
Give examples of hydracids
HCl, HBr, HI
What are oxyacids?
Acids containing hydrogen, another element and oxygen
Give examples of oxyacids
HNO3, H2SO4
What does the strength of an acid depend on?
It depends on the concentration of hydronium ions present in an aqueous solution of an acid
What does the strength of an alkali depend on?
On the concentration of hydroxyl ions present in an aqueous solution of the alkali
What is a strong acid?
An acids which dissociates almost completely in aqueous solution thereby producing a high concentration of hydrogen [H+ ions] [or H3O+] ions
What does a strong acid contain?
Almost only ions
Give two equations representing the dissociation of a strong acid
HNO3 + H2O ⇌ H3O+ + NO3-
H2SO4 + 2H2O ⇌ 2H3O+ + SO4 2-
What is a strong alkali?
It is an alkali which dissociates almost completely in aqueous solution thereby producing a high concentration of hydroxyl [OH-] ions
What does a strong alkali consist of?
Almost only ions (contains solute molecules in addition to water molecules)
Give two equations representing the dissociation of a strong alkali
NaOH [aq] ⇌ Na+ + OH-
KOH [aq] ⇌ K+ + OH-
Give examples of strong acids
Hydrochloric, Sulphuric and Nitric acid
Give examples of strong alkalis
Lithium, Sodium, Potassium hydroxide
What is a weak acid?
It an acid which dissociates only partially in aqueous solution thereby producing a low concentration of hydrogen [H+] ions [or H3O+ ions]
What is a weak alkali?
It is an alkali which dissociates only partially in aqueous solution thereby producing a low concentration of hydroxyl [OH-] ions
Give an equation representing the dissociation of a weak acid
CH3COOH ⇌ CH3COO- + H+
Give an equation representing the dissociation of a weak alkali
NH4OH [aq] ⇌ NH4+ + OH-
What does a weak acid consist of?
Molecules and ions
What does a weak alkali consist of?
Molecules and ions
Give examples of weak acids
Acetic, citric, carbonic, formic acid
Give examples of weak alkalis
Ammonium hydroxide and Calcium hydroxide
How are crystals of glacial acetic acid formed?
On cooling of anhydrous acetic acid
What is a concentrated acid?
It is an acid having a relatively high percentage of acid in its aqueous solution
What is a concentrated alkali?
It is an alkali having a relatively high percentage of alkali in its aq. solution
What is a dilute acid?
It is an acid having a relatively low percentage of acid in its aqueous solution
What is the concentration of acid in a dilute acid?
Less than 1 mole/litre
What is a dilute alkali?
It is an alkali having a relatively low percentage of alkali in its aq. solution
What is the concentration of alkali in a dilute alkali?
Less than 1 mole/litre
What is the basicity of acids?
The no. of hydrogen ions [H+] which can be produced per molecule of the acid in aq. soln. or the no. of hydroxyl ions with which one molecule of an acid combines
What is a monobasic acid?
It ionizes in aq. soln. to produce one hydrogen ion per molecule of the acid. Or contains one replaceable hydrogen ion per molecule of the acid
In how many steps do monobasic acids dissociate in aq. soln.?
In one step
Name the salts monobasic acids form
They form only one type of salt [normal salt]
Give examples of monobasic acids
HCl, HNO3, CH3COOH
How many hydrogen atoms does acetic acid have?
4, but it ionizes in aq. soln. to produce one hydrogen ion per molecule of the acid
What is a dibasic acid?
It ionizes in aq. soln. to produce two hydrogen ions per molecule of the acid. Or contains two replaceable hydrogen ions per molecule of the acid
In how many steps do dibasic acids dissociate?
Two steps
Name the types of salts dibasic acids form
2 types - acid and normal salt
Give examples of dibasic acids
H2SO3, H2SO4, H2CO3
What is a tribasic acid?
It ionizes in aq. soln. to produce three hydrogen ions per molecule of the acid. Or contains three replaceable hydrogen ions per molecule of the acid
In how many steps do tribasic acids dissociate?
Three steps
Name the types of salts tribasic acids form
Three salts - two acid, one normal - have three replaceable hydrogen atoms
Name a normal salt
Trisodium phosphate
What is the acidity of bases?
The no. of hydroxyl ions [OH-] which can be produced per molecule of the base in aq. soln. or the no. of hydrogen ions with which a molecule of a base combines
What is a monoacidic base?
It ionizes in aq. soln. to produce one hydroxyl ion per molecule of the base or contains one replaceable hydroxyl ion per molecule of the base [if water soluble]
In how many steps does a monoacidic base dissociate?
In one step
Give examples of monoacidic bases
NaOH, KOH, NH4OH
What is a diacidic base?
It ionizes in aq. soln. to produce two hydroxyl ions per molecule of the base or contains two replaceable hydroxyl ions per molecule of the base [if water soluble]
In how many steps does a diacidic base dissociate?
One step
Give examples of diacidic bases
Ca(OH)2, Zn(OH)2, Cu(OH)2
What is a triacidic base?
It ionizes in aq. soln. to produce three hydroxyl ions per molecule of the base or contains three replaceable hydroxyl ions per molecule of the base [if water soluble]
In how many steps does a triacidic base dissociate?
One step
Give examples of triacidic bases
Al(OH)3, Fe(OH)3 [water insoluble]
What is the Arrhenius theory?
Acids are substances which dissociate in aqueous solution to give H+ ions. Strong acids dissociate almost completely, while weak acids dissociate partially
What is Lowry-Bronsted’s theory?
Acids are proton donors. Bases are proton acceptors
]proton = H+].
How does water exhibit charge separation?
The H atom of water carries a slight positive charge and the O atom, a slight negative charge
How many lone pairs of electrons does oxygen atom have in water?
Oxygen atom has two lone pairs of electrons not shared with any other atom
How does the formation of H3O+ ion come about from acid in aq. soln.?
- A proton (H+ ion) released from HCl adds on to the lone pair of electrons of oxygen atom of water molecule.
- The H1+ ion accepts the lone pair of electrons forming a coordinate covalent bond
Why does the H+ proton released from HCl add on to the lone pair of electrons of the oxygen atom of the water molecule?
Oxygen atom in H2O has a slight negative charge
What is a coordinate covalent bond?
The bond formed between the atom of a polar covalent molecule with lone pair of electrons and an ion which accepts the lone pair of electrons
How does the formation of OH- ion come about from alkalis in aq. soln.?
- A proton (H+ ion) released from water adds on the lone pair of electrons of the nitrogen atom of the ammonia molecule
- The H+ ion accepts the lone pair of electrons forming a coordinate covalent bond
How many lone pairs of electron does nitrogen in ammonia have?
1 lone pair
Why does the H+ ion released from water add on to the lone pair of electrons of the nitrogen atom of ammonia molecule?
Nitrogen atom of ammonia molecule has a slight negative charge
Name the ways acids are prepared
- From Non-Metals
- From Acidic Oxides
- From Salts
- By oxidation of non-metals
How are acids prepared from non-metals?
Reaction of non-metals with hydrogen gives an acid
Hydrogen + Non-metal -> Acid
Give equations to show the preparation of acids from non-metals
H2 + Cl2 -> 2HCl
H2 + I2 -> 2HI