Acids & Bases Flashcards

1
Q

What are the 3 physical properties of acids?

A
  1. Acids taste sour
  2. Dilute acids are irritants and will result in rashes and blisters
  3. Acids turn blue litmus paper red
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2
Q

What makes a compound/substance an acid?

A

If it dissociates H+ ions when dissolved in water

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3
Q

Acid + Metal ——> ?

A

Salt + H2

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4
Q

Acid + Base ——> ?

A

Salt + H2O

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5
Q

Acid + Metal carbonate ——> ?

A

Salt + H2O + CO2

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6
Q

What type of reaction is this? Acid + Base ——> Salt + H2O

A

Neutralisation reaction

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7
Q

How do you differentiate between strong acids and weak acids? Give an example of a strong and weak acid.

A

Strong acids have the ability to dissociate fully in water to produce a high concentration of H+ ions. Weak acids only have the ability to dissociate partially in water to produce a low concentration of H+ ions. Hydrochloric acid is a strong acid while hydrofluoric acid is a weak acid.

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8
Q

Explain concentration of an acid.

A
  • Concentration of acid is dependent on how diluted the solution is (the dilution factor)
  • Concentration refers to number of acid molecules present per water molecule
  • Usually expressed in mol/dm-3
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9
Q

What is basicity of an acid?

A

The basicity of an acid depends on the acid’s chemical formula. Basicity refers to number of H+ ions produced per molecule. For example, HCl produces 1 H+ ion and is monobasic, H2SO4 produces 2 H+ ions and is dibasic, H3PO4 produces 3 H+ ions and is tribasic

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10
Q

Can a strong acid have a low concentration of H+ ions?

A

Yes, use a strong acid like nitric acid and add a large amount of water to it.

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11
Q

If we dissolve 2 strong acids, nitric acid and sulfuric acid, in water, which one will produce a higher concentration of H+ ions?

A

Even though both strong acids will dissociate fully in water, sulfuric acid would produce a higher concentration of H+ ions. Sulfuric acid is dibasic, producing 2 H+ ions per molecule while nitric acid is monobasic, producing only 1 H+ ion per molecule.

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12
Q

What is a base?

A

A base is defined as a substance which reacts with an acid to form a salt and water only. All metal oxides and hydroxides are bases.

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13
Q

What are alkalis?

A

Alkalis are a special group of bases that are soluble in water. Hence, alkalis dissociate either fully or partially in water to produce OH- ions, giving rise to its alkaline properties. In other words, alkalis are a subset of base.

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14
Q

The oxides and hydroxides of metals in which 2 groups of the periodic table form alkalis?

A

Group l and Group II

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15
Q

Name the 4 physical properties of alkalis

A
  1. Alkalis taste bitter
  2. Dilute alkalis feel slippery and soapy to touch
  3. Concentrated alkalis are caustic, causing chemical burns
  4. Alkalis turn red litmus paper blue
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16
Q

What makes a compound/substance an alkali?

A

A compound is considered an alkali when it dissociates OH- ions when it dissolves in water.

17
Q

What is a weak alkali?

A

A weak alkali is one that only dissociates partially in water to produce a low concentration of OH- ions.

18
Q

What must you take note of when writing the dissociation reaction for a weak alkali or acid? And why?

A
  • Must write the reversible sign ⇌. Since it is a weak alkali, some of the ions may turn back to the atom.
  • A commonly used weak alkali is aqueous ammonia. Dissociation reaction for ammonia is NH3 + H2O ⇌ NH₄⁺ + OH-. Some NH₄⁺ ions turn back to NH3, resulting in low concentration of OH- ions produced.
19
Q

What are the 4 uses of alkalis?

A
  1. Toothpaste to neutralise acid on teeth
  2. Calcium hydroxide used to neutralise acidity in soil
  3. Magnesium hydroxide in indigestion tablets, aka antacid pills
  4. Sodium hydroxide in floor & cleaners
20
Q

Alkali + Ammonium salt ——> ?

A

Salt + H2O + NH3 (g)

21
Q

Why must litmus paper be moist when testing for ammonia gas?

A

Moist litmus paper must be used in order for the ammonia gas to dissolve in water and dissociate to form OH- ions.

22
Q

If HCl (aq) is hydrochloric acid, does this mean HCl (l) which is hydrogen chloride, an acid as well?

A

No. An acid is only considered as an acid after it has dissociated in water and H+ ions are formed. This is the same for alkali. An alkali is only an alkali after it has dissociated in water and formed OH- ions.

23
Q

What must you remember when writing dissociation reaction for weak alkalis?

A

Must add water. For example, write NH3 + H2O ⇌ NH₄⁺ + OH- and not NH3 ⇌ NH₄⁺ + OH-.

24
Q

The pH scale ranges from 0 to 14. pH 7 is considered neutral. pH 14 is considered very _____ and ph 1 is considered very _____.

A

Alkaline; acidic

25
Q

The indicator methyl orange is _____ when acidic, _____ when neutral and _____ alkaline.

A

Red; orange; yellow

26
Q

The indicator screened methyl orange is _____ when acidic, _____ when neutral and _____ alkaline.

A

Purple; grey; green

27
Q

The indicator phenolphthalein is _____ when acidic, _____ when neutral and _____ alkaline.

A

Colourless; pale pink; pink

28
Q

The indicator bromothymol blue is _____ when acidic, _____ when neutral and _____ alkaline.

A

Yellow; green; blue