acids and redox Flashcards
sulfuric acid
H2SO4
nitric acid
HNO3
acid
release H+ in aq sol
alkali
release OH- in aq sol
strong acid
fully dissociates in sol- rel all of H+
weak acid
partially dissociates- rel small prop oh available H atoms as H+
what does the ebm sign indicate
the forwards reaction is incomplete
example of weak acid
CH3CH2COOH- ethanoic acid
neutralisation reaction
reaction of H+ and OH- to form water
neutralisation reactions of acids and bases
acid+metal (hydr)oxide-> salt and water
acid+carbonate-> CO2+H2O+salt
alkali
water soluble base
standard solution
sol of a known conc
uses of titrations
finding conc of a sol
identifying unknown chemicals
finding the purity of a substance
why is checking impurities important
medicines and food
impurities can cause harm to patients
100cm3 volumetric flask
+/- 0.20cm3
250cm3 volumetric flask
+/- 0.30cm3
preparing standard solution
weigh solid dissolve w/distilled water transfer sol to VF, rinse traces fill until bottom of meniscus touches graduation line invert several times
effect on titre if volumetric flask filled above graduation line
titre would be less as sol is more dilute
how can you accurately fill the flask
view the graduation mark and and meniscus at eye level
why is flask inverted
to mix the solution evenly thoroughly
effect on titre if flask not inverted
sol used in first titration would be more dilute than sol used later
first titre would need less solution
how can you tell the solution mixing as you invert the flask
able to see the more dense original sol move through the sol
burette reading
nearest +/- 0.05cm3
2dp
how to remove air bubbles from burette
when filling run XS sol through tap
acid-base titration procedure
add meas vol of sol in c.flask using pipette
add another sol to burette, record initial
few drops of indicator to c.flask
run sol in burette into sol in c.flask, swirl, end point
record final burette reading
quick trail, repeat until 2 concordant titres
swirl c.flsk
to mix the 2 sols
indicator
identify when end point is reacted
end point
vol of one sol the exactly reacts w/ the vol of 2nd sol
titre
vol of sol added from the burette
how to calculate the titre
initial- final burette reading
trail titration
to find the approximate titre
concordant
agreeing w/in 0.10cm3
how is titration repeated accurately
adding sol dropwise as endpoint is approached
effect on titre if air bubble inside pipette
titre would be less as less sol has been added than the correct pipette volume
effect on titre if readings taken from burette at top of the meniscus rather that bottom
no effect as vol is measured by difference bw 2 readings
including all titres in the mean
lose accuracy
method for analysing results
moles of solute- n=cV
moles of other solute- ratio
unknown info about solute in the other sol