Acids and Bases (C4) Flashcards

(84 cards)

1
Q

What does pH measure?

A

Acidity or Alkalinity

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2
Q

What is indicator?

A

A dye that changes colour depending on its pH

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3
Q

Is pH 7 acid or alkali?

A

Neutral

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4
Q

Is pH 5 acid or alkali?

A

Acid

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5
Q

Is pH 9 acid or alkali?

A

Alkali

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6
Q

Is pH 14 acid or alkali?

A

Strong Alkali

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7
Q

Is pH 1 acid or alkali?

A

Strong Acid

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8
Q

What can we use to judge pH?

A

pH probe or indicator

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9
Q

Define Acid

A

Substances that form aqueous solutions with a pH below 7

They form H+ ions in water

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10
Q

Define Base

A

A substance with a pH greater than 7

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11
Q

Define Alkali

A

A base dissolved in water to form a solution greater than 7

Alkalis form OH- ions in water

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12
Q

Neutralisation Reaction

A

Base + Acid = Water + Salt

BAWS

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13
Q

Neutralisation Reaction in terms of ions

A

H+(aq) + OH- = H2O(l)

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14
Q

What is titration for?

A

They allow you to find exactly how much acid is needed to neutralise an alkali or vie versa.

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15
Q

What is the first step of a titrartion?

when you are finding the concentration of an alkali needed for the neutralisation of an acid

A

Use a pippette and pippette filler, add a set volume (25cm^3) of the alkali to a conical flask. Add a few drops of indicator.

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16
Q

What is the second step of a titrartion?

when you are finding the concentration of an alkali needed for the neutralisation of an acid

A

Use a funnel to fill a burette with acid. Make sure you do this below eye level. Record the initial volume of the acid in the burette.

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17
Q

What is the third step of a titrartion?

when you are finding the concentration of an alkali needed for the neutralisation of an acid

A

Add acid slowly from the burette into the conical flask, swirlig constantly until you see the end-point. This is visible when the colour changes.

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18
Q

What is the fourth step of a titrartion?

when you are finding the concentration of an alkali needed for the neutralisation of an acid

A

Record the final volume of the acid in the burette and use it to calculate the volume of acid needed to neutralise the alkali.

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19
Q

What should you do to increase the accuracy of your titration?

A

You should take several consstent results. Take only answers within 0.1cm^3 of each other and ignore any anomalous results.

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20
Q

Why is universal indicator not ideal for titrations?

A

It changes colour gradually

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21
Q

What indicators are best for titrations?

A

Single indicators

litmus, phenolphthalein, methyl organge

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22
Q

What colour does litmus paper turn?

A

Blue in alkalis and red in acids.

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23
Q

What colour does phenolphthalein turn?

A

Pink in alkalis and colourless in acids and neutral

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24
Q

What colour does methyl orange turn?

A

Yellow in alkalis and red in acids

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25
What is a strong acid?
Fully ionising in an aqueous solution | They produce H+ hydrogen ions
26
What is a weak acid?
Weak acids do not fully ionise in aqueous solutions. Only a small proportion of acid particles dissociate to release H+ ions.
27
Examples of strong acids
Sulphuric Acid Hydrochloric Acid Nitric Acid
28
Examples of weak acids
Ethanoic Acid Citroc Acid Carbonic Acid
29
The ionisation of which acids is reversible?
Weak Acids
30
What is pH?
Concentration of H+ ions
31
If the concentration of H+ ions in an acid that was pH 4 is increased by a factor of 10, what is the pH now?
pH5
32
Which has a higher pH, strong acid or weak acid?
Weak acid has a higher pH than strong acid
33
Reaction between acid and metal oxide
``` Metal Oxide (Base) + Acid = Water + Salt BAWS ```
34
Reaction between acid and metal hydoxide
``` Metal Hydroxide (Base) + Acid = Water + Salt BAWS ```
35
What is salt produced in a reaction between hydrochloric acid and a metal?
Metal chloride
36
What is salt produced in a reaction between sulphuric acid and a metal?
Metal sulphate
37
What is salt produced in a reaction between nitric acid and a metal?
Metal nitrate
38
Reaction between acid and metal carbonate
Metal Carbonate + Acid = Water + Carbon Dioxide + Salt | CAWCS
39
Name 3 types of bases
Metal oxides Metal hydroxides Metal carbonates
40
Which base does not form a BAWS reaction?
Metal Carbonates form a CAWCS reaction (with carbon dioxide)
41
How do you make a soluble salt from an insoluble base?
- Gently warm the dilute acid on a bunson burner, then switch off - Add the base, stirring until it sinks to the bottom (it will be in excess at this point) - Filter out excess base - Gently heat the solution in a water bath or electric heater to evaporate water - Stop heating and allow to cool - Filter and dry the crystals
42
What process seperates an insoluble?
Crystallisation
43
What is the reactivity series?
Order of metal reactivity
44
Which non-metals are in the reactivity series?
Hydrogen and Copper
45
How reactive is Potassium (K)
Very
46
How reactive is Copper (Cu)
Not very
47
How reactive is Carbon (C)
Fairly
48
How reactive is Lithium (Li)
Very
49
How reactive is Hydrogen (H)
Not very
50
How reactive is Sodium (Na)
Very
51
How reactive is Magnesium (Mg)
Fairly
52
How reactive is Iron (Fe)
Fairly
53
How reactive is Calcium (Ca)
Very
54
How reactive is Gold (Au)
Not - It's a native metal
55
How reactive is Zinc (Zn)
Fairly
56
Define Native Metal
Usually found in their pure form, pretty much unreactive
57
What forms if an acid reacts with a metal?
Acid + Metal = Salt + Hydrogen
58
Test for Hydrogen
Squeaky Pop test | Place a lit splint near it, you should hear a 'squeaky-pop-
59
Which metals will readily undergo a reaction with acids?
Anything more reactive than hydrogen
60
What forms if water reacts with a metal?
Metal + Water = Metal Hydroxide + Hydrogen
61
Which metals will readily undergo a reaction with water?
Potassium (K) Sodium (Na) Lithium (Li) Calcium (Ca)
62
Define Oxidation
(Gain of oxygen) | Loss of electrons
63
Define Reduction
(Loss of oxygen) | Gain of electrons
64
How do we extract metals with low reactivity from their ores?
Reduction using carbon | anything less reactive than carbon
65
How do we extract metals with high reactivity from their ores?
Electrolysis | anything more reactive than carbon
66
Why can highly reactive metals not be extracted with carbon?
This reduction is a displacement reaction, more reactive metals will not be displaced by carbon
67
What type of reaction is reduction using carbon?
Displacement Reaction
68
What is a displacement reation?
When a more reactive element takes the place of a less reactive one in a compound
69
What is a redox reaction?
A reaction where electrons are transferred
70
Oxygen is essential to an oxidation or reduction reaction. True or False?
False | Any electron loss or gain classifies as a reduction or oxidation
71
What do we call an ion which does not change in a reaction?
Spectator ions
72
Define Electrolysis
Using an electrical current to 'split' a metal compound into its elements
73
Why must a metal compound be molten or aqueous during electrolysis?
So that the ions can move freely
74
Where does the positive ion go during electrolysis?
Cathode (negative electrode)
75
Where does the negative ion go during electrolysis?
Anode (positive electrode)
76
What do we call the molten or aqueous solution during electrolysis?
Electrolyte
77
What happens during electrolysis of a molten solution?
Two rods (electrodes) with electrical current are placed in the electolyte Metals (positive ions) are attracted to the negative electrode Non - metals (negative ions) are attracted to the positive electrode These can then be collected in their pure form
78
What is used to lower the melting point of metal compounds such as aluminium oxide, to make a molten solution?
Cryolite
79
What is aluminum ore called?
Bauxite
80
What happens at the negative elctrode?
The positive metal ion is attracted to the negative electrode. Here it gains electrons (reduction) and becomes its element.
81
What happens at the positive elctrode?
The negative non-metal ion is attracted to the positive electrode. Here it looses electrons (oxidation) and becomes its element.
82
What additional ions are involved in the electrolysis of an aqueous solution?
H+ and OH-
83
When does hydrogen form at the cathode?
Electrolysis of an aqueous solution if hydrogen is less reactive than the metal
84
When does oxygen form at the annode?
Electrolysis of an aqueous solution if no halide ions are present (Cl2, Br2 etc..)