acids and bases Flashcards
acids
substances that are able to produce H+ ions when dissolved in water. Cause litmus to go red, phenolphthalein to go colourless and methyl orange to go red
bases
substances that can neutralise acids
alkalis
soluble bases that produce OH- ions when in water. They cause litmus to go blue, phenolphthalein to go pink and methyl orange to go yellow
bronsted lowry definitions
acids are proton H+ donors
bases are proton H+ acceptors
for a species to act as an acid it must contain a hydrogen atom attached by a bond which can be easily broken
for a species to act as a base it must contain a non bonding e- pair which it csn use to form a coordinate bond with an H+ ion.
conjugate acids and basses
when an acid donates H+ the species produced is called a conjugate base as it now has the ability to accept an H+
when a base gains H+ the species produced is called a conjugate acid as it now has the ability to donate an H+
the stronger the acid the weaker the conjugate base it produces and the weaker the acid the stronger the conjugate base
amphiprotic
substances (eg water) which are able to either donate or accept a H+ and so act as either an acid or a base are said to be ampiprotic
amphoteric
a substance that can act as either an acid or a base. this is a more general term as not all acids lose or gain H+ ions.
strong and weak acids in aqueous solution
strong acids ionise completely in aqueous solution
weak acids partially ionise in aqueous solution
strong acids therefore have higher concentrations of hydrogen ions in aqueous solution when compared to a weak acid of the same concentration
experimental determination of strength of acids
- conductivity: strong acids are able to conduct electricity much better than weaker acids
- by reaction with Carbonates: the one that produces CO2 at the greatest rate is the strongest.
- pH: the lower the pH value, the higher the concentration of H+, the stronger the acid
pH
pH stands for power of hydrogen
pH = -log10[H+]