Acids And Bases Flashcards

1
Q

What is an acid? (Arrhenius definition)

A

An acid is a substance that produces hydrogen ions in solution

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2
Q

Give an example of an acidic reaction for the Arrhenius definition of an acid

A

HCl –(H2O)–> H+ + Cl-

HCl dissolves (ionises) in water to H+ + Cl-

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3
Q

What is a base? (Arrhenius definition)

A

a base is a substance that produces hydroxide ions in solution

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4
Q

Give an example of a basic reaction (Arrhenius definition)

A

NaOH dissociates in water to form aqueous solution of Na+ ions and OH-

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5
Q

What is the Bronsted-Lowry model of acids and bases describe?

A

An acid reacting to form its conjugate base and a base reacting to form its conjugate acid

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6
Q

What is an acid? Bronsted-Lowry definition

A

Acid is a proton donor

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7
Q

What is a base?

Bronstd-Lowry definition

A

A base is a proton accepter

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8
Q

Give an example of a bronsted-Lowry model of acids and bases and also give an explanation to why it helps.

A

H-Cl + H2O ➡️ Cl- + H3O
(Acid) + (Base) ➡️ (Conjugate base of acid HCl) + (conjugate acid of H2O)

This model of acids and bases helps to explain why some substances are basic even though hydroxide ions are not produced in solution

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9
Q

What is an amphoteric?

A

A substance that can accept or donate a proton

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10
Q

What is an amphoteric substance?

A

Water is considered to be amphoteric as it can donate a proton to form an hydroxide ions or accept a proton to form the hydronic ion (H3O+)

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11
Q

What do acids taste like?

A

Sour

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12
Q

What do bases taste like?

A

Bitter

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13
Q

What colour does acids turn litmus?

A

Red

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14
Q

What colour do bases turn litmus?

A

Blue

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15
Q

What pH do acids have?

A

pH below 7 at 25C

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16
Q

What pH do bases have?

A

pH above 7 at 25C

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17
Q

Are acids sticky or slippery?

A

may feel sticky

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18
Q

Are bases sticky or slippery?

A

may feel slippery

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19
Q

Do acids and bases both conduct electricity when in solution?

A

YAS

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20
Q

Are both acids and bases corrosive?

A

YAS

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21
Q

What do acids react with?

A

React with metals, metal oxides, metal hydroxides, metal carbonates and metal hydrogen carbonates.

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22
Q

What do bases react with?

A

Reacts with acids, oils and fats

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23
Q

What are the 8 type of acid/base reactions?

A
Acid and metal
Acid and metal hydroxide
Acid and metal oxide
Acid and carbonate
Acid and hydrogen carbonate 
Acid and metal sulfite
Base and ammonium salt
Base and non-metal oxide
24
Q

Acid and Metal —> ?

A

Acid and Metal —> Salt and H2 (gas)

eg. 2HCl(aq) + Ni(s)—> NiCl2(aq) + H2(g)

25
Q

Acid and Metal Hydroxide —> ?

A

Acid and Metal Hydroxide —> Salt + H2O

eg. 2HNO3(aq) +Ca(OH)2(s) —> Ca(NO3)2 (aq) + 2H2O (l)

26
Q

Acid and Metal Oxide —> ?

A

Acid and Metal Oxide —> Salt + H2O

eg. H2SO4 + CuO —> CuSO4 + H2O

27
Q

Acid and Carbonate —> ?

A

Acid and Carbonate —> Salt + H2O + CO2

28
Q

Acid and Hydrogen carbonate —> ?

A

Acid and Hydrogen carbonate —> Salt + H2O +CO2

29
Q

Acid and Metal Sulfite —> ?

A

Acid and Metal Sulfite —> Salt + H2O + SO2

eg. 2HCl(aq) + Na2SO3(s) —> 2NaCl(aq) + H2O(l) + SO2(g)

30
Q

Base and Ammonium salt —> ?

A

Base and Ammonium salt —> Salt + H2O +NH3(g)

eg. KOH(aq) + NH4Cl (aq) —> KCl(aq) + H2O(l) + NH3(g)

31
Q

Base + Non-Metal oxide (acid) —> ?

A

Base + Non-Metal oxide (acid) —> Salt + H2O
eg. 2KOH(aq) + SO2(g) —> K2SO3(aq) + H2O(l)
2NaOh(aq) + CO2(g) —> H2O(l) + NaCO3

32
Q

What is an indicator?

A

a substance that changes colour depending on the

concentration of hydronium (hydrogen) ions present.

33
Q

What is pH?

A

pH is a measure of the hydronium (hydrogen) ion concentration in a solution
and is calculated using the formula:
pH = - log [H3O+]

34
Q

What is the H3O+ concentration for ph 1, 2, 3

A

pH 1 = 1.Ox10^-1
pH 2 = 1.Ox10^-2
pH 1 = 1.Ox10^-3

The change of one pH unit is equivalent to a ten-fold change in the hydronium ion concentration

35
Q

Give an example of when the concentration of hydronium ions is equal to the concentration of hydroxide ions

A

For pure water at 25C the concentration of hydronium ions is equal to the concentration of hydroxide ions and the pH is exactly 7. At 25C a pH of 7 is called neutral (neither acidic or basic).

36
Q

What are some strong acids (6)

A
HCl  
H2SO4
HNO3
HI
HBr
HClO4
37
Q

What are some weak acids? (7)

A
H2SO3
H3PO4
HF
CH3COOH
H2CO3
Ammonium salts (NH4Cl, NH4NO3)
38
Q

What are some strong bases? (4 types)

A

oxides of group 1 metals

  • Li2O
  • K2O
  • Na2O

oxides of group 2 metals

  • MgO
  • CaO
  • BaO

Hydroxides of group 1 metals

  • LiOH
  • NaOH
  • KOH

Hydroxides of group 2 metals

  • Mg(OH)2
  • Ba(OH)2
39
Q

What are some weak bases? (4 types)

A

Metal Phosphates

  • Na3PO4
  • K3PO4

Metal carbonates

  • Na2CO3
  • K2CO3

metal hydrogen-carbonates

  • NaHCO3
  • KHCO3
  • Ca(HCO3)2

AMMONIA

  • NH3
  • NH3OH
40
Q

Are non-metal oxides are acidic? and also describe a reaction of non-metal oxides with water.

A

many non-metal oxides are acidic, though it is not immediately apparent from Arrhenius theory.

Non-metal oxides like CO2 and SO3 combine with water to form acids then acids ionise to form H+ and acidic solution

41
Q

Give an example of a reaction of non-metal oxides with water

A

When added to water, SO2 initially dissolves to form H2SO3 which then partially ionises forming hydrogen ions, this lowers the solutions pH.

SO2 + H2O ↔️ H2SO3
then H2SO3 + H2O ↔️ H3O+ + HSO3-
overall SO2 + 2H2O ↔️ H3O+ + HSO3-

42
Q

Are metallic oxides basic or amphoteric like Na2O or CaO basic? and also describe a reaction of metallic oxides?

A

they are basic or amphoteric in nature and are not immediately obvious from Arrhenius theory.

  • Dissociation releases positive metal ions and O2- (aq) -
  • then rapidly combines with H2O to produce OH-(aq) -
  • when dissolve in H2O a metal oxide converts into a basic solution of corresponding metal hydroxide
43
Q

Give a example of a reaction of a metallic oxides with water

A

Na2O dissolves…. Na2O(s) —> 2Na+(aq) + O2- (aq)

Oxides ion reacts with water…. O2-(aq) + H2O(l) —> 2OH-(aq)

Overall….. Na2O(s) + H2O (l) —-> 2Na+(aq) + 2OH- (aq)

44
Q

What happens when the metallic oxide is insoluble?

A

CaO and MgO will absorb water to produce an hydroxide

eg. CaO(s) + H2O —-> Ca(OH)2 (s)

MgO(s) + H2O —-> Mg(OH)2 (s)

45
Q

What is a polyprotic acid?

A

A polyprotic acid is one that has more than one acidic hydrogen atom

eg.
H2SO4
HSCO3
H3PO4

46
Q

What is are strong electrolytes?

A

Strong acids and all ionic compounds

47
Q

What are weak electrolytes?

A

Weak acids or bases

48
Q

What is dissociation?

A

When an ionic solid dissolves in water

49
Q

What is ionisation?

A

When a covalent molecular substance dissolves in water to form ions.

50
Q

Why do partially ionised/dissociated reactions occur?

A

as a weak electrolyte or non-electrolyte is used

51
Q

What are non-electrolytes?

A

most covalent molecular substances, as they don’t conduct electricity when molten or in aqueous solution

52
Q

What happens when an acid and ammonia react?

A

H attaches to the NH3 (not H2O) to produce NH4+

eg. HCl(aq) + NH3(aq) —-> NH4Cl(aq)

53
Q

What happens when ammonia reacts with water?

A

Ammonia is considered a weak base due to the production of OH- ions when it reacts with water,

NH3(g) + H2O(l) —> NH4+ + OH-

54
Q

What happens when ammonium salt reacts with a base?

A

ammonium ion is considered to be a weak acid. Meaning it will react with a base to produce a salt and water, however ammonia gas will also be produced in the reaction

NaOH + NH4Cl —> NaCl(aq) + NH3(g) +H2O

55
Q

Name 6 acidic ions

A
NH4+
Al3+
Fe3+
HCO3-
H2PO4-
HSO4-
56
Q

Name 3 basic ions. And a one weakly base.

A

SO4^2-
CO3^2-
HCO3-

PO4^3-