Acids And Bases Flashcards

0
Q

What is the Arrhenius definition of a base?

A

It is a substance that dissolves is water to produce OH- ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
1
Q

What is the Arrhenius definition of an acid?

A

It is a substance that dissolves in water to produce H+ (H3O+) ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is a Bronster-Lowry Acid?

A

It is a proton donor

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is a Brønsted-Lowry base?

A

It is a proton acceptor

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What is a conjugate acid-base pair?

A

Any pair of molecules or ions that can be interconverted by transfer of a proton (aka when an acid turns into its conjugate base or when a base turns into its conjugate acid)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What do strong acids and bases do in water?

A

Completely ionize

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What do weak acids and bases do in water?

A

Partially ionize

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Pka=?

A

-logKa

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Stronger acids have _____Ka values and therefore ______pKa values

A
  1. ) Larger

2. ) Smaller

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Some common weak organic acids are:

A
  • Carboxylic acids

- Compounds containing the -COOH group (carboxyl)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

The position of equilibrium in an acid base reaction favors reaction of the _____ acid (____pKa value) with the _____base to form the ______ acid (______pKa value) and the _____ base.

A
  1. ) Stronger
  2. ) Lower
  3. ) Stronger
  4. ) Weaker
  5. ) Higher
  6. ) Weaker
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What is thermochemistry?

A

The study of energy of the entire system at each moment of a reaction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

If the products are more stable than reactants, the overall thermodynamics are favorable for reaction and the step is ______

A

Exergonic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

If products are less stable than reactants, the overall thermodynamics are not favorable for reaction and the step is ______

A

Endergonic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

What is kinetics?

A

The study of rates of chemical reactions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

The lower the free energy of activation, the _____ the rate of the reaction

A

Faster

16
Q

What is enthalpy?

A

It is the energy contained within chemical bonds and solvation

17
Q

What happens in an exothermic reaction?

A

Heat is released because bonds are formed in the product that are stronger than the bonds that were broken in the starting material

18
Q

What happens in an endothermic reaction?

A

The bonds formed in the product are weaker than those broken in the starting materials, so heat is absorbed

19
Q

What is entropy?

A

Entropy is the measure of chaos

20
Q

What is a Lewis Acid?

A

It is a species that can form a new covalent bond by accepting a pair of electrons

21
Q

What is a Lewis Base?

A

It is a species that can form a new covalent bond by donating a pair of electrons

22
Q

All Brønsted-Lowry acids (_____) are also Lewis acids

A

Proton donors

23
Q

All Bronster Lowery bases (________) are also Lewis Bases

A

Proton acceptors