Acids and Bases Flashcards
How to form an effective buffer
High concentration and ratio of [base]/[acid]=0.1-10
Which one is more acidic? HF or HI
HI. Size↑, charge spread over greater volume.
Which one is more acidic? H2O or CH4
H2O. More electronegative
Which one is more acidic? [Fe(H2O)6]3+ or Fe(H2O)5(OH)2+
[Fe(H2O)6]3+. Charge of the metal ion ↑, radius ↓, attract electron density from O, proton is more readily to lose.
Arrange the increasing base strength of (CH3)3N, H3N, F3N
F3N<H3N<(CH3)3N
Arrange the increasing acid strength of (CH3)3B, H3B, F3B
(CH3)3B< H3B< F3B
Hard metal ion
alkali metal ions, alkaline earth metal ions and highly charged ions
Soft metal ion
transition metal, low charged ions
Arrange the acids from hard to soft. Br-, F-, Cl-, I-
F->Cl->Br->I-