Acids And Bases Flashcards
Ph table
Acids
<7 and 1 is most acidic
H+»_space; OH-
Red litmus paper stays red and turns blue litmus paper red
Neutral
=7
H+=OH-
Red litmus paper stays red and blue litmus paper stays blue
Basic
>7 and 14 is the most basic
H+«OH-
Red litmus paper turns blue and blue litmus stays blue
Conjugate acids and bases
Definition
The Bronsted-Lowry definition of acids and bases
To show that a compound is acidic or basic, we write its reaction with water
An Acid donates protons to water to form hydronium ions (H3O+)
A Base accepts protons from water to form hydroxide ions (OH-)
NH3 + H2O ↔ OH- + NH4+
Base = Proton Acceptor
HCl + H2O ↔ H3O+ + Cl-
Acid = Proton donor
Conjugate Acid Base pairs
For every acid there is a conjugate base. For example: if H2O is the acid then OH- is the conjugate base
Similarly for every base there is a conjugate acid. If OH- is the base and H2O is the conjugate acid.
NH3 + H2O ↔ OH- + NH4+
HCl + H2O ↔ H3O+ + Cl-
Amphiprotic substances
Amphiprotic Substances
→ some substances can both accept and donate protons depending on what they are reacting with, they are called amphiprotic substances.
HCO3- + H2O ↔ H3O+ + CO3-2
HCO3- + H2O ↔ OH- + H2CO3
water is another important amphiprotic substance.
Strong acids
STRONG ACIDS
→ are fully dissociated
have a high K value (Ka) - so lots of products, H3O+
Equilibrium lies to the right - so lots of products
Strong acids have:
→ good conductivity
(as high [ions])
→ Low PH
(as high [H3O+])
→ Fast reaction rate
(as high [H3O+])
Examples of Strong acids
→ HCl
→ H2SO4
→ HNO3
Weak acids
Weak acids
→ are partially dissociated
have a low K value (Ka) - so [low] of products, H3O+
Equilibrium lies to the left - so lots of reactants
Weak acids have:
→ Poor conductivity
(as low [ions])
→ Higher PH (still?)
(as lower [H3O+])
→ Slow reaction rate
(as low [H3O+])
Examples of weak acids
→ CH3COOH
→ HCOOH
→ HF
Strong bases
Strong Bases
→ are ionic and therefore fully dissociated
have a high K value (Kb) - so lots of products, OH-
Equilibrium lies to the right - so lots of products
Strong bases have:
→ Good Conductivity
(as high [ions])
→ high pH
(as high [OH-])
→ Fast reaction rate
(as high [OH-])
Examples of Strong bases
→ NaOH
→ KOH
→ Any metal hydroxide
Weak bases
- Weak bases→ have partially reacted with waterhave a low K value (Kb) - so [low] of products, OH-Equilibrium lies to the left - so lots of reactantsWeak bases have:→ Poor conductivity(as low [ions])→ Lower PH (still?)(as lower [OH-])→ Slow reaction rate(as low [OH-])Examples of weak bases→ NH3→ Amines→ HBr