acids and bases Flashcards

1
Q

definition of an acid

A

substance that ionises to form hydrogen ions when dissolved in water

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2
Q

physical properties of acids

A

pH <7
sour taste
electrolytes that can conduct electricity

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3
Q

strong acids vs weak acids

A

completely ionises vs partially ionises
reversible vs irreversible reaction
pH 1-3 vs pH 3-7

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4
Q

what does higher basicity mean

A

higher concentration of H+ ions for. the same concentration of acid

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5
Q

which metals are unreactive

A

copper, silver

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6
Q

definition of an alkali

A

substance that dissociates to form hydroxide ions when dissolved in water

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7
Q

properties of alkalis

A

ph >7
bitter taste; slippery and soapy
electrolytes

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8
Q

bases vs alkalis

A

all alkalis are bases, but not all bases are alkalis
bases are insoluble in water while alkalis are soluble in water
bases and alkalis react with acids to produce a salt and water and react with ammonium salts to produce a salt, water, and ammonia

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9
Q

how to calculate pH

A

-lg [concentration of H+ ions]

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10
Q

types of oxides

A

basic oxides (react with acids, metal oxides)
amphoteric oxides (react with both acids and bases) (zinc, aluminium, lead (II)

acidic oxides (react with bases, non-metal oxides)
neutral oxides (react with neither acids nor bases) (water, carbon monoxide, nitric oxide, dinitrogen monoxide)

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11
Q

characteristics of oxides across periodic table

A

change from basic to amphoteric to acidic across a period

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12
Q

what is a salt

A

ionic compound formed by the replacement of one or more hydrogen ions of an acid by a metallic ion of ammonium ion

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13
Q

solubility of carbonates in water

A

all insoluble except sodium, potassium, ammonium

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14
Q

solubility of chlorides in water

A

all soluble except silver, lead (II)

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15
Q

solubility of nitrates in water

A

all soluble

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16
Q

solubility of sulfates in water

A

all soluble except barium, lead (II), calcium (sparingly soluble)

17
Q

how to prepare insoluble salt

A

precipitation
react 2 aqueous substances

18
Q

how to prepare soluble salts (non spa salts)

A

reaction of acid with insoluble substance (metal, base, or carbonate)

insoluble substance in excess of acid to ensure salt is not contaminated

19
Q

how to prepare soluble salts (spa salts)

A

titration (reaction of acid with alkali / soluble carbonate)
both reactants soluble in water, titration allows for exact volume to be used to obtain a pure salt

20
Q

why are spa salts prepared using titration

A

all their compounds are soluble, hence they cannot be prepared through reactions of acids with insoluble substances

since salt and reactants are soluble in water, using indicator ensures that exact volumes of reactants needed for complete reaction is added with no excess of either reactant, allowing a pure salt to be obtained