acids and bases Flashcards

1
Q

pH

A

The pH of a solution is a measure of its hydrogen ion concentration and thus its acid-base characteristics. High hydrogen ion concentration, that is an acidic solution, corresponds to a low pH. Basic solutions have a high pH. Pure water is neutral and has a pH of seven. Dissolving an acid or base in water will change his pH. Adding an acid raises the concentration of hydrogen ions thus Lowering the pH. Adding a base to water raises the hydroxide ion concentration and causes the hydrogen ion concentration to fall causing the pH to rise.

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2
Q

arrhenius theory: acids

A

an acid is a substance that will ionise in a solution producing H+ (aq) ions.

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3
Q

arrhenius theory: bases

A

A base is a substance that will dissociate in solution releasing OH- (aq) ions

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4
Q

acids: oxides

A

non-metal oxides

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5
Q

bases: oxides

A

metal oxides/hydroxides

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6
Q

ionisation

A

Acids have a covalent molecular structure and so don’t actually contain hydrogen ions. However, when dissolved in the water they produce hydrogen ions in a reaction called ionisation. This will result in the formation of hydrogen ions

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7
Q

dissociation

A

Bases are all ionic hydroxide compound. These compounds contain metal ions and hydroxide ions. When dissolved in water these ions are released into solution. This process is called dissociation

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8
Q

strong acids

A

Arrhenius theory States that strong acids dissolve in water to undergo complete ionisation. Thus all the dissolved acid converts into ions. A single arrow in the ionisation equation shows this.

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9
Q

strong acids vs weak acids

A

always produce a more vigorous reaction than weak acids
a strong acid will produce a higher hydrogen ion concentration than weak acids

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10
Q

weak acid

A

the theory identifies a weak acid as one that undergoes partial ionisation which means that the remaining is mostly in the form of unionised molecules. Double arrows show the partial nature of this reaction.

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11
Q

strong acids: examples

A
  • HCl (hydrochloric acid)
  • H2SO4 (sulfuric acid)
  • HNO3 (nitric acid)
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12
Q

weak acids: examples

A
  • CH3COOH (ethanoic acid)
  • C6H8O7 (citric acid)
  • H2CO3 (carbonic acid)
  • H3PO4 (phosphoric acid)
  • H2SO3 (sulfurous acid)
  • HSO4- (hydrogen sulfate ion)
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13
Q

strong bases

A

strong bases are group 1 or 2 metal oxides/hydroxides
- NaOH (sodium hydroxide)
- Ca(OH)2 (calcium hydroxide)
- MgO (magnesium oxide)

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14
Q

weak bases

A
  • CuO (copper (II) oxide)
  • NH3 (ammonia)
  • NaHCO3 (sodium hydrogencarbonate)
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15
Q

acids: characteristics

A
  • tastes sour
  • cause indicators to change colour to red
  • are corrosive
  • many solutions of acids conduct electricity
  • reacts with carbonates to form carbon dioxide and water
  • react with some metals to form hydrogen
  • react with bases to form bases
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16
Q

bases: characteristics

A
  • taste bitter
  • feel slippery
  • cause indicators to change colour to blue
  • can be corrosive
  • do not react with most metals
  • many solutions of bases conduct electricity
  • react with acids to form water
17
Q

conjugate

A

acid:
loss of H+
HCl -> Cl- (conjugate base)

base:
gain of H+
NH3 -> NH4+ (conjugate acid)

18
Q

electrolytes

A

solutions of ions

19
Q

strong electrolytes

A

def: completely ionises
strong electrolytes have all dissolved molecules ionise in solution, there are no molecules left only ions present in water

20
Q

examples of strong electrolytes

A

all ionic compounds (what does dissolve goes into ions), if insoluble will still be a strong electrolyte but will have low conductivity

strong acids and strong bases: SA: HCl, HNO3, H2SO4, SB: group 1 and group 2 metal oxides and hydroxides

21
Q

weak electrolytes

A

definition: partially ionises, only some dissolved molecules ionise in solution, there will be neutral molecules and some ions present in the water

22
Q

examples of weak electrolytes

A

weak acids and bases:
WA: CH3COOH, H3PO4, H2CO3, WB: NH3

23
Q

non-electrolytes

A

definition: doesn’t ionise, all remain as neutral species in solution

24
Q

examples of non-electrolytes

A

most covalent substances that aren’t acids or bases e.g. sugar (C6H12O6), sucrose, kerosene and ethanol

25
Q

hydronium ion

A

H3O+ is an ion that is formed through the protonation of water
H2O + H+(ion) → H3O+