acids and bases Flashcards
pH
The pH of a solution is a measure of its hydrogen ion concentration and thus its acid-base characteristics. High hydrogen ion concentration, that is an acidic solution, corresponds to a low pH. Basic solutions have a high pH. Pure water is neutral and has a pH of seven. Dissolving an acid or base in water will change his pH. Adding an acid raises the concentration of hydrogen ions thus Lowering the pH. Adding a base to water raises the hydroxide ion concentration and causes the hydrogen ion concentration to fall causing the pH to rise.
arrhenius theory: acids
an acid is a substance that will ionise in a solution producing H+ (aq) ions.
arrhenius theory: bases
A base is a substance that will dissociate in solution releasing OH- (aq) ions
acids: oxides
non-metal oxides
bases: oxides
metal oxides/hydroxides
ionisation
Acids have a covalent molecular structure and so don’t actually contain hydrogen ions. However, when dissolved in the water they produce hydrogen ions in a reaction called ionisation. This will result in the formation of hydrogen ions
dissociation
Bases are all ionic hydroxide compound. These compounds contain metal ions and hydroxide ions. When dissolved in water these ions are released into solution. This process is called dissociation
strong acids
Arrhenius theory States that strong acids dissolve in water to undergo complete ionisation. Thus all the dissolved acid converts into ions. A single arrow in the ionisation equation shows this.
strong acids vs weak acids
always produce a more vigorous reaction than weak acids
a strong acid will produce a higher hydrogen ion concentration than weak acids
weak acid
the theory identifies a weak acid as one that undergoes partial ionisation which means that the remaining is mostly in the form of unionised molecules. Double arrows show the partial nature of this reaction.
strong acids: examples
- HCl (hydrochloric acid)
- H2SO4 (sulfuric acid)
- HNO3 (nitric acid)
weak acids: examples
- CH3COOH (ethanoic acid)
- C6H8O7 (citric acid)
- H2CO3 (carbonic acid)
- H3PO4 (phosphoric acid)
- H2SO3 (sulfurous acid)
- HSO4- (hydrogen sulfate ion)
strong bases
strong bases are group 1 or 2 metal oxides/hydroxides
- NaOH (sodium hydroxide)
- Ca(OH)2 (calcium hydroxide)
- MgO (magnesium oxide)
weak bases
- CuO (copper (II) oxide)
- NH3 (ammonia)
- NaHCO3 (sodium hydrogencarbonate)
acids: characteristics
- tastes sour
- cause indicators to change colour to red
- are corrosive
- many solutions of acids conduct electricity
- reacts with carbonates to form carbon dioxide and water
- react with some metals to form hydrogen
- react with bases to form bases