Acids & Alkalis F4 Flashcards
Definition of an indicator
An indicator is a chemical which is one colour in acid and another in alkali
Red litmus in acid
Stays red
Red litmus in alkali
Turns blue
Blue litmus in acid
Turns red
Blue litmus in alkali
Stays blue
Phenolphalein in acid
Stays colourless
Phenolphalein in alkali
Turns pink
Methyl Orange in acid
Turns pink
Methyl Orange in alkali
Turns yellow
Advantages of an indicator
- Shows different colours for acids and alkalis
Disadvantages of an indicator
- Don’t tell us relative strengths
- Limited in their use
Universal indicators
Indicate the STRENGTH of the substance
pH of strong acid
0 - 2
pH of weak acid
3 - 6
pH of weak alkali
8 - 11
pH of strong alkali
12 - 14
Strong Acids
- Hydrochloric Acid
- Nitric Acid
- Sulfuric Acid
Weak Acids
- Ethanoic Acid
- Carbonic Acid
Neutral Substances
- Water
- Petrol
- Ethanol
Weak Alkalis
- Ammonia
Strong Alkalis
- Sodium Hydroxide
- Potassium Hydroxide
Definition of an acid
Substance which dissolves in water to produce HYDROGEN IONS.
What is a strong acid?
One which is completely ionised in water and contains a high concentration of Hydrogen ions.
What is a weak acid?
One which is partially ionised in water and contains a low concentration of Hydrogen ions.
Definition of an alkali
A soluble base which dissolves in water to produce HYDROXIDE IONS.
What is a weak alkali?
One which is partially ionised in water
Definition of a base
Metal oxide or metal hydroxide
Definition of concentration
How much of the original acid is dissolved in the solution
Definition of neutralisation
Reaction between hydrogen ions of an acid and hydroxide ions of an alkali to produce water
METAL + ACID
SALT + HYDROGEN (MASH)
ACID + METAL OXIDE (base) =
SALT + WATER
ACID + CARBONATE =
SALT + WATER + CARBON DIOXIDE
ACID + HYDROGEN CARBONATE =
SALT + WATER + CARBON DIOXIDE
ACID + AMMONIA =
AMMONIUM SALT
Copper (II) Oxide colour and in solution
Black - (-)
Copper (II) Carbonate colour and in solution
Green - (-)
Copper (II) Sulfate colour and in solution
Blue - (-)
Group 1 / 2, Al & Zn compounds
White - Colourless
METAL + ACID Observations
- Heat
- Effervescence
- Metal disappears
- Colourless solution
ACID + (HYDROGEN) CARBONATE Observations
- Heat
- Effervescence
- Metal (hydrogen) carbonate disappears
- Solution produced
(coloured - transition metal)
(clear - group 1 & 2)
Test for Hydrogen
Lighted splint on mouth of test tube with Hydrogen gas burns in air with squeaky pop
Test for Carbon Dioxide
Bubble Carbon Dioxide through limewater. Limewater turns from colourless to milky white.
What is an endothermic reaction?
A reaction that takes in heat.
What is an exothermic reaction?
A reaction that gives out heat. (all neutralisation reactions)
What is a calorimeter?
Experimental apparatus used to measure temperature.
What is a Salt?
A compound formed when some / all of the hydrogen ions in an acid are replaced by metal ions.
Soluble Salts from Insoluble Bases / Acids
- 25cm of acid into conical flask
- warm acid & add metal oxide until saturated
- filter mixture
- heat solution
- leave to cool
Soluble Salts from Soluble Bases / Alkalis
- fill burette with dilute acid
- pipette 25cm alkali to conical flask
- 3 drops of phenolphalein
- add acid from burette and mix
- stop adding acid at end point (pink to colourless)
- record volume of acid added
ALTERNATIVE PROCEDURE for Soluble Bases / Alkalis
- repeat titration with fresh samples of alkali until 2 concordant results are obtained
- repeat titration without indicator
- heat in evaporating basin
- leave to cool
Chemical equation for Hydrogen
Hydrogen + oxygen = water