Acids, Alkalis and Salts Flashcards
Describe the method of salt solution preparation (using an insoluble solid and an acid)
- Warm approx. 20cm3 of acid in a boiling tube using a water bath
- Add acid into a beaker
- Gradually add insoluble solid to the acid and stir until it is in excess
- Use filter paper and a funnel to filter the contents of the beaker
Describe the method of crystallisation
- Pour filtered solution of the salt solution in an evaporating basin
- Heat using a Bunsen burner (or leave for a week) until it is saturated - crystals form on glass rod when dipped in the salt solution
- Leave it in a cool place for at least 24hrs to let it cool down and crystallise
- Filter the remaining fluid from the crystals
- Gently pat dry the crystals
General word equation
Metal + acid -> ?
Salt + hydrogen
General word equation
Alkali + acid -> ?
Salt + water
General word equation
Base + acid -> ?
Salt + water
General word equation
Carbonate + acid -> ?
Water + carbon dioxide + salt
General word equation
Ammonia + acid -> ?
Ammonium salt
All acids contain ________ ions
Hydrogen (H+)
All alkalis contain _________ ions
Hydroxide (OH-)
Litmus in acids, neutrals and alkalis
Acid: red
Neutral: purple
Alkali: blue
Phenolphthalein in acids, neutrals and alkalis
Acid: colourless
Neutral: colourless
Alkali: pink
Methyl orange in acids, neutrals and alkalis
Acid: red
Neutral: orange
Alkali: yellow
Universal indicator in acids, neutrals and alkalis
Acids: red
Neutral: green
Alkalis: blue/purple
Acids are proton ______
Donors
Bases are proton _________
Acceptors
Neutralisation (give equation)
When an acid reacts with an alkali it produces a salt and water
H+ (aq) + OH- (aq) -> H2O (l).
SPA (Sodium, Potassium, Ammonium) salts are all…
Soluble
All nitrates are…
Soluble
All chlorides are _______ except…
Soluble, except silver chloride and lead II chloride
All sulfates are _______ except…
Soluble, except calcium sulfate, barium sulfate and lead II sulfate
All hydroxides are _________ except… (what is special about a certain hydroxide?)
Insoluble except SPA salts and calcium hydroxide is slightly soluble
All carbonates are _________ except
Insoluble, except SPA salts
Titration (soluble salt)
- Use a pipette to transfer exactly 25cm3 of an alkali to a conical flask
- Add 3 drops of methyl orange indicator to the conical flask
- Fill the burette with acid and ensure that there are no air bubbles
- Run a little acid out into a beaker to fill the jet
- Record initial volume of acid in the burette
- Add acid to the alkali in the conical flask, swirling the conical flask all the time
- As the indicator begins to change colour, add the acid dropwise until there is a permanent colour change
- Record final volume of acid in burette
- Repeat titration until 2 results are condordant (within 0.20cm3)
- Repeat without indicator, adding mean value of acid to obtain a pure salt for crystallisation
Precipitation (insoluble salt)
- Mix 2 solutions
- Filter precipitate
- Wash with distilled water
- Dry (no need for crystallisation)
Crystallisation
- Pour solution into an evaporating basin
- Heat basin gently until a saturated solution is formed (dip glass rod into solution to see if crystals form)
- Stop heating and allow solution to cool to form large crystals
- Filter remaining liquid after and blot dry