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Chemistry > A - Polymers > Flashcards

A - Polymers Flashcards

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1
Q

What is a condensation reaction?

A

A reaction where two molecules react together and a small molecule, mostly water (but could be HCl), is eliminated.

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2
Q

What does condensation polymerisation usually involve?

A

Usually involves two different types of monomer, each with at least two functional groups.

Each functional group reacts with a group on another monomer to form a link, creating polymer chains.

Each time a link is formed, a small molecule is lost (water).

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3
Q

Give some examples of condensation polymers.

A

Polyamides, polyesters, polypeptides and proteins.

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4
Q

How can you form a polyamide?

A

By reacting a dicarboxylic acid with a diamine.

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5
Q

What is a dicarboxylic acid?

A

A molecule with two carboxylic acid groups.

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6
Q

What is a diamine?

A

A molecule with two amine groups.

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7
Q

What is repeated in a polyamide?

A

The amide linkage -CONH- is repeated over and over.

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8
Q

Outline what happens, and what is formed, in the condensation polymerisation reaction between a dicarboxylic acid and a diamine.

A

The carboxyl group of the dicarboxylic acid reacts with the amino group of the diamine to form amide links in the polyamide.

Dicarboxylic acids and diamines have functional groups at each end of the molecule, so long chains can form.

A water molecule is eliminated with each amide link formed.

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9
Q

Give two examples of polyamides.

A
  1. Nylon 6,6

2. Kevlar

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10
Q

What are the monomers that make up nylon 6,6?

A

1,6-diaminohexane and hexanedioic acid.

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11
Q

What is the formula for 1,6-diaminohexane?

A

H2N(CH2)6NH2

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12
Q

What is the formula for hexanedioic acid?

A

HOCO(CH2)4OCOH

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13
Q

What is the formula for nylon 6,6? What is the repeating unit?

A

[HN(CH2)6NHCO(CH2)4CO]n

The repeating unit is the bit inside the square brackets.

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14
Q

What are the monomers that make up Kevlar?

A

1,4-diaminobenzene and benzene-1,4-dicarboxylic acid.

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15
Q

What is the formula for 1,4-diaminobenzene?

A

H2N(benzene ring)NH2

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16
Q

What is the formula for benzene-1,4-dicarboxylic acid?

A

HOOC(benzene ring)COOH

17
Q

What is the formula for Kevlar? What is the repeating unit?

A

[HN(benzene ring)NHCO(benzene ring)CO]n

The repeating unit is the bit inside the square brackets.

18
Q

What are some typical uses of nylon 6,6?

A

Used to make clothing, carpet, rope, airbags and parachutes.

19
Q

What are some typical uses of Kevlar?

A

Used in bulletproof vests, boat construction, car tyres and lightweight sports equipment.

20
Q

Why is Kevlar so strong?

A

Due to the rigid chains and the ability of the flat aromatic rings to pack together held by strong intermolecular forces.

21
Q

How are polyesters formed?

A

By a reaction between dicarboxylic acids and diols.

22
Q

Outline the condensation polymerisation reaction, and the products formed, between dicarboxylic acids and diols.

A

The carboxyl groups of dicarboxylic acids react with the hydroxyl groups of diols to form ester links to form polyesters.

Water is eliminated with each ester link formed.

23
Q

Give an example of a polyester.

A

Terylene (PET).

24
Q

What monomers form Terylene (PET)?

A

Benzene-1,4-dicarboxylic acid and ethane-1,2-diol.

25
Q

What are the typical uses of Terylene (PET)?

A

Used in plastic bottles, clothing, sheets and sails.

26
Q

Explain the nature of the intermolecular forces between molecules of condensation polymers.

A

Condensation polymers are generally stronger and more rigid than addition polymers.

This is because condensation polymers are made up of chains containing polar bonds, e.g C-N and C-O. So there are hydrogen bonds between the polymer chains, as well as permanent dipole-dipole forces and Van der Waals forces which are also present.

27
Q

How do you identify the repeating unit of a condensation polymer?

A

This is found by starting at any point in the polymer and stopping when the same pattern of atom begins again.

28
Q

How do you identify the monomer(s) of a condensation polymer?

A
  1. Start with the repeating unit.
  2. Break the linkage (at the C-O for a polyester or C-N for a polyamide).
  3. Add back the components of water for each ester or amide link.
29
Q

Why are polyalkenes chemically inert and non-biodegradable? Give some examples of polyalkenes.

A

They are addition polymers made up of non-polar carbon chains. This is what makes them unreactive and chemically inert, and non-biodegradable.

Examples: poly(ethene) and polystyrene.

30
Q

Why are condensation polymers biodegradable? Do they degrade quickly?

A

They have polar bonds in their chains, which makes them open to attack from nucleophiles. This means that they can be broken down by hydrolysis and are biodegradable, although this process is very slow.

31
Q

Why is the question about how we dispose of plastics (synthetic polymers) so important?

A

Because plastics either take a very long time to biodegrade or are non-biodegradable.

32
Q

What are the four options of disposing of plastics?

A
  1. Burying
  2. Burning
  3. Reusing
  4. Recycling
33
Q

When are plastics sent to the landfill to be buried?

A

When the plastic is:

  1. Difficult to separate from other waste
  2. Not in sufficient quantities to make separation financially worthwhile
  3. Too difficult technically to recycle.
34
Q

What are the pros and cons of using the landfill to bury plastics?

A

Pros:
1. It’s relatively cheap and easy method of waste disposal.

Cons:

  1. Required areas of land.
  2. As waste decomposes, it can release methane (a greenhouse gas).
  3. Leaks from landfill sites can contaminate water supplies.
  4. We’re producing large amounts of waste so there is a need to reduce landfill as much as possible.
35
Q

Discuss burning as a method of plastic disposal.

A

Waste plastics can be burned and the heat can be used to generate electricity.

This process must be controlled to reduce the release of toxic gases e.g polymers containing chlorine, such as PVC, produce HCl when burned which is toxic and must be removed.

Waste gases from the combustion are passed through scrubbers to do this which can neutralises gases such as HCl by allowing them to react with a base.

But waste gases such as CO2 still contribute to the greenhouse effect.

36
Q

After sorting plastics, what are the different methods of recycling them?

A
  1. Some plastics, such as poly(propane) for example, can be melted and remoulded.
  2. Some plastics can be cracked into monomers, and these can be used to make more plastics or other chemicals.
37
Q

What are the advantages of recycling?

A
  1. Reduces amount of waste going to landfill.
  2. Saves raw materials (important as oil is non-renewable).
  3. Cost of recycling plastics is lower than making plastics from scratch.
  4. Produces less CO2 emissions than burning plastics.
38
Q

What are the disadvantages of recycling plastics?

A
  1. It’s technically difficult.
  2. Collecting, sorting and processing the plastic is more expensive than burning/landfill.
  3. You often can’t remake the plastic you started with, you have to make something else.
  4. The plastic can be easily contaminated during the recycling process.

Chemistry (34 decks)

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