A Level Organic Flashcards
Carboxylic Acids
-Have -oic acid ending.
-Always at the end of the chain.
-Numbering always starts from carboxylic acid end.
-If there’s COOH on both sides, it is called a -dioic acid.
Acidity of carboxylic acids
-Weak acids in water and only slightly dissociate.
-Strong enough to displace CO2 from carbonates.
Solubility in water of carboxylic acids
-Smaller carboxylic acids dissolve in water in all proportions.
-Bigger chains have lower solubility.
-The dissolve easily because they can hydrogen bond to the water molecules.
Delocalisation of carboxylic acids
-Salts are stabilised by delocalisation.
-Makes dissociation more likely.
-Have equal C-O bond lengths.
-Pi charge cloud delocalises and spreads out and makes ion more stable and more likely to form.
Strength of carboxylic acids
-Increasing chain length pushes electron density on to the COO- ion.
-This makes it more negative and less stable- less strong.
-Electronegative chlorine atoms withdraw electron density from COO- ion.
-This makes it less negative and more stable- more strong.
Carboxylic acid + Metal —>
Salt + Hydrogen
-Example- (CH3COOH + Na –> CH3COO-Na+ + 1/2 O2)
Carboxylic acid + Alkali —>
-Salt + Water
-Example- (CH3COOH + NaOH —> CH3COO-Na+ + H2O)
Carboxylic acid + Carbonate —>
-Salt + Water + Carbon dioxide
-Example- (CH3COOH + 1/2Na2CO3 –> CH3COO-Na+ +1/2H2O + 1/2CO2)
Oxidation of methanoic acid
-Carboxylic acids can’t be oxidised by oxidising agents but methanoic acid is an exception as its structure has an aldehyde group.
-H-COOH + [O] —> HOCOOH
-Forms carbonic acid (H2CO3) which can decompose to give CO2.
Esterification
-Carboxylic acids react with alcohols in the presence of a strong acid catalyst to form esters and water.
Use of esters
-Esters are sweet smelling compounds that can be used in perfumes and flavourings.
-Esters can be used as solvents for polar organic substances.
-Ethyl ethanoate is used as a solvent in glues and printing inks.
-Esters can be used as plasticisers for polymers.