✅9 - Kinetics I Flashcards

1
Q

What is collision theory?

A

Particles must collide to react

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What are the criteria for particles to react?

A

They must collide in the right orientation

They must collide in with the minimum amount of kinetic energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is activation energy?

A

The minimum amount of kinetic energy needed to for the particles to react

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What is a reaction profile diagram?

A

Shows the progress of the reaction over time, with the energy of the reactants and products

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What happens when the temperature is increased?

A

Reactions progress faster

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

How does higher temperature change the Maxwell-Boltzman distribution?

A

It moves to the right

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Why does increasing temperature speed up a reaction?

A

The molecules have more kinetic energy and so collide more often

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Why does increasing concentration speed up a reaction?

A

If you increase the concentration of reactants in solution, there are more particles in a given volume of the solution, so they collide more frequently

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Why does increasing pressure speed up a reaction?

A

If any of the reactants are gases, there are more molecules of the gas in the volume so there are more successful collisions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Why do catalysts speed up reactions?

A

They lower the activation every by providing a different way for bonds to be broken, and then more molecules have the required energy to react

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What does rate of reaction tell you?

A

How fast reactants are converted to products

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

How can rate of reaction be worked out?

A

From the gradient of a graph

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

How would you calculate gradient?

A

Change in y / change in x

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

How would you work out the gradient of a curved graph?

A

By drawing a tangent

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

How can you work out the initial rate of reaction?

A

By calculating the gradient of the intial part of the graph

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

How can you work out rates of reaction from experimental data?

A

amount of reactant used or amount of product made/time taken

17
Q

What is the rate of reaction proportional to?

A

1/time

18
Q

Why does a catalyst increase the rate of reaction?

A

By providing an alternative pathway for the reaction

19
Q

What is a benefit of using a catalyst?

A

They don;t get used u in reactions so only a small amount is needed

20
Q

What is a disadvantage of using a catalyst?

A

They are very specific

21
Q

What is a heterogeneous catalyst?

A

One in a different phase to the reactants

22
Q

What do solid heterogeneous catalysts provide?

A

A surface for the reaction to take place on

23
Q

How do heterogeneous catalysts work?

A

The reactant molecules are adsorped, then the bonds are weakened and the new molecules are formed. Then, they are desorped

24
Q

What is a homogeneous catalyst?

A

One in the same physical state as the reactants

25
Q

How do homogeneous catalysts work?

A

They combine with the reactants to make an intermediate species, then forming the products

26
Q

What economic benefits do catalysts have?

A

They lower costs of production, make more products in a shorter time and make better products

27
Q

What catalyst is used in ammonia production?

A

Iron

28
Q

How does polyethene behave when made without a catalyst?

A

It is less dense and less rigid

29
Q

How does polyethene behave when made with a catalyst

A

It is more dense, more rigid and has a higher melting point

30
Q

What does the Maxwell-Boltzmann distribution show?

A

The proportion of particles with a certain amount of energy