9 Enthalpy Flashcards

1
Q

What is enthalpy?

A

Enthalpy is a measure of the heat energy in a chemical system.

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2
Q

What is a chemical system?

A

The chemical system refers to the atoms, molecules, or ions making up the chemicals.

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3
Q

How do we calculate enthalpy change?

A

Enthalpy of products-enthalpy of reactants

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4
Q

What describes an exothermic change?

A

Energy transfer from the system to the surroundings.

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5
Q

What describes an endothermic change?

A

Energy transfer from the surroundings to the system.

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6
Q

Is enthalpy change positive or negative in an exothermic reaction?

A

Enthalpy change is negative.

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7
Q

Is enthalpy change positive or negative in an endothermic reaction?

A

Enthalpy change is positive.

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8
Q

What is activation energy?

A

The minimum energy required for a reaction to take place.

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9
Q

Why do reactions with small activation energies take place quickly?

A

Reactions with small activation energies take place very rapidly because the energy needed to break bonds is readily available from the surroundings.

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10
Q

What are the standard conditions?

A

A standard physical value.

1) Standard pressure: 100kPa
2) Standard temperature: 298K
3) Standard concentration: 1moldm-3
4) Standard state: The physical state of a substance under standard conditions.

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11
Q

What is the standard enthalpy change of reaction?

A

The enthalpy change that accompanies a reaction in the molar quantities expressed in a chemical equation under standard conditions, all reactants and products being in their standard states.

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12
Q

What is the standard enthalpy change of formation?

A

The enthalpy change that takes place when one mole of a compound is formed from its constituent elements in their standard states under standard conditions.

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13
Q

What is the standard enthalpy change of combustion?

A

The enthalpy change that takes place when one mole of a substance reacts completely with oxygen under standard conditions all reactants and products being in their standard states.

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14
Q

What is the standard enthalpy change of neutralisation?

A

The enthalpy change that accompanies a reaction of an acid by a base to form one mole of H2O, under standard conditions with all reactants and products in their standard states.

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15
Q

What does specific heat capacity mean?

A

The energy required to raise the temperature of 1g of a substance by 1°C.

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16
Q

What does average bond enthalpy mean?

A

The average bond enthalpy is the energy required to break one mole of a specified type of bond in a gaseous molecule.

17
Q

What is Hess’s law?

A

If a reaction can take place by more than one route and the initial and final conditions are the same, the total enthalpy change is the same for each route.

18
Q

What is the formula for calculating energy change?

A

q=mcT

massspecific heat capacitytemp change

19
Q

How do you calculate the enthalpy change of formation?

A

Products-reactants

20
Q

How do you calculate the enthalpy change of combustion?

A

Reactants-products

21
Q

Why is experimental value sometimes less exothermic than data book value?

A
  • Heat loss to surroundings
  • Incomplete combustion of methanol
  • Evaporation of methanol from wick
  • Non-standard conditions