9: Chemistry of the Atmosphere Flashcards

1
Q

what percentage of different gases are in air?

A

nitrogen - 78%; oxygen - 21%; argon - 0.9%; CO2 - 0.04%`

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2
Q

what was the main composition of the early earth’s atmosphere?

A

due to intense volcanic activity, large amounts of carbon dioxide and water vapour were released, and smaller amounts of nitrogen, hydrogen, ammonia, methane and other gases - little to no oxygen

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3
Q

how were oceans formed?

A

while surface of Earth was still v hot, water vapour was mainly gaseous; once conditions cooled sufficiently, water vapour condensed & fell to surface forming oceans

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4
Q

how did CO2 levels decrease in the early atmosphere?

A

large amounts of CO2 dissolved in the oceans; carbonate substances were precipitated during this process; marine life began to evolve sea creatures used up the carbonates to form shells and skeletons, later formed sediments; plants photosynthesising used it up; being trapped in fossil fuels and sedimentary rocks.

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5
Q

how did oxygen levels increase?

A

plants and algae evolved and began photosynthesizing which used up CO2 and released oxygen

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6
Q

describe the greenhouse effect.

A

shortwave radiation from the sun is absorbed by earth’s surface and is re-emitted from surface as infrared (longwave) radiation; this long wave radiation is absorbed by the greenhouse gas layer, keeping the earth warm

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7
Q

what are sources CO2 emissions (now)?

A

combustion of wood and fossil fuels; respiration of plants and animals; thermal decomposition of carbonate rocks and the effect of acids on carbonates

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8
Q

what are sources methane emissions (now)?

A

digestive processes of animals; decomposition of vegetation; bacterial action in swamps and in rice paddy fields

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9
Q

why is there uncertainty about models of the early atmosphere?

A

the methods used are not as precise as modern day techniques nor do they provide data which is representative on a global scale

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10
Q

what are the consequences of climate change on humanity?

A

changes in rainfall patterns may lead to uneven distribution of water, causing flooding in some regions and drought in others; may lead difficulties in obtaining fresh drinking water

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11
Q

what are the consequences of climate change on Earth’s natural systems and processes?

A

melting of the polar ice caps, flooding and flash fires = the destruction of ecosystems; changes in temperature will affect the distribution of wildlife

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12
Q

what is a carbon footprint?

A

the amount of carbon dioxide released into the atmosphere as a result of the activities of a particular individual, organization, or community

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13
Q

why is it difficult to get an exact carbon footprint?

A

there are so many different factors to consider - e.g. sources materials; manufacturing

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14
Q

how can we reduce our carbon footprint?

A

use renewable energy supplies; conserve (use less) energy; carbon capture and storage; carbon taxes and licences; carbon off-setting (planting more trees)

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15
Q

why are there difficulties when reducing ghg emissions?

A

expensive equipment for switching over to alternative energy resources; governments tend to be slow to act - fear a negative impact on their economies; a lack of investment schemes for companies to help them to modernize their facilities; still lots of research to be done on alternative technologies

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16
Q

what is produced in complete/incomplete combustion?

A

complete: CO2 and H2O
incomplete: CO/C and H2O

17
Q

how is sulfur dioxide produced?

A

sulfur impurities present in the fuels react with oxygen during combustion to produce sulfur dioxide;

18
Q

how are nitric oxides produced?

A

produced in the reaction of nitrogen with oxygen at high temperatures and pressure in car engines and high-temperature furnaces and as a product of bacterial action in soil

19
Q

why is sulfur dioxide and nitric oxides bad?

A

dissolves in rainwater and forms acid rain - can affect fresh water ponds and lakes and destroy the aquatic life; can cause respiratory problems, irritates throats and eyes; causes corrosion to metal structures, buildings and statues made of carbonate rocks; nitric oxides also produce smog