8 for exam Flashcards
Linear
2 or 3 atoms in a straight bond
Bent
V shaped structure of three atoms
Trigonal Planar
Triangle with atoms on one plane. 4 atoms
Pyramidal
3D triangle in a pyramid shape. 4 atoms
Tetrahedral
Central atom (carbon atom) with 4 attachments. 5 atoms in total.
Bond polarity
- extent
- contributes
Unequal sharing of electrons from atoms of different elements as they have differing electronegativity creates partial positive and partial negative area. Extent is determined by differences in electronegativity. Contributes to the overall molecular polarity.
Electronegativity in covalent bonds
- determines
Ability of an atom to attract electrons towards its nucleus.
Determine bond polarities which contribute to overal polarity
Permanent dipole
Result of atoms with vastly different electronegativities bonded together creating an uneven distribution of electron density. Experience a net dipole, have a perminent positive and negative end.
Overall polarity
If the molecule has a net dipole moment from the individual bond dipoles not canceling out
Intermolecular forces
Attractive forces that exist between neighbouring molecules. Crucial role in determining bpt, VP and solubility
Temporary dipoles
Happens due to electron movement which creates momentary areas of higher electron density. Which makes a temporary negative dipole.
Intramolecular forces
- types
- holds
Bonds within covalent molecules can be polar (different atoms bonded) or non polar (covalent bond with atoms of the same element so same electronegativity). Holds molecules together
3 main types of intermolecular forces
- dispersion
- DP-DP
- hydrogen bonding
Dispersion forces
- due to
- how does it increase
Temporary dipoles that can occur within molecules. ALL molecules (polar and non polar) will form dispersion forces and as molar mass increases (increased number of electrons), dispersion increases.
Dispersion forces
‘As molar mass increases’
As molar mass increases the number of electrons increases therefore the number of and strength of temporary dipoles increases. Therefore the magnitude of dispersion forces between neighbouring molecules increases.