7.0 Oxidation, reduction, and redox reactions Flashcards
What is oxidation in terms of oxygen?
The gain of oxygen
What is oxidation in terms of electrons?
The loss of electrons
What does an oxidising agent do?
Donate oxygen/accept electrons (it is reduced)
What is reduction in terms of oxygen?
The loss of oxygen
What is reduction in terms of electrons?
The gain of electrons
What does a reducing agent do?
Accept oxygen/donate electrons (it is oxidised)
What are redox reactions?
Reactions in which both oxidation and reduction occur
What are used to see what has been oxidised and
what has been reduced in a redox reaction?
Oxidation states or oxidation numbers
What is the oxidation state for an element?
Zero
What is the oxidation state of a metal in its
compound?
The charge on the ion that it forms
What is the oxidation state of a hydrogen, H atom in a compound?
It is +1 unless in a hydride e.g. NaH, where it is -1
What is the oxidation state of an oxygen, O atom in a compound?
It is -2 unless it is in a peroxide e.g. H2O2 and compounds with F, where it is -1
What is the oxidation state of chlorine, Cl atom in a
compound?
It is -1 unless when bonded to F and O, where it can have positive values
What is disproportionation?
A redox reaction in which the oxidation state of some atoms of a particular element increases in oxidation state and of others decrease in oxidation state
What are the 5 rules for constructing a balanced half
equation for compounds that contain oxygen?
- Write down the reactants and products and
balance any non-oxygen atoms that appear on
both sides of the equation - Balance oxygen atoms with water (H2O)
- molecules
Balance hydrogen atoms with hydrogen ions (H+).
Balance the charges with electrons
Check the equation balances using the charges
and oxidation states
- molecules
What are the 3 rules for constructing a balanced redox equation?
- Construct both half-equations
- Make sure that the number of electrons in each
half equation are the same, so that the electrons
cancel out
Add the half-equations and cancel the electrons
and other species that appear on both sides of
the equation
- Make sure that the number of electrons in each
What are the 3 rules for constructing half-equations
from a balanced redox equation?
- Write the oxidation state above each element in
the balanced redox equation
Use the oxidation states to identify what
reactants have been oxidised and reduced
Construct the half-equations for these identified
reactants
- Write the oxidation state above each element in