7. Valence Shell Electron Pair Repulsion (VSEPR) Flashcards

1
Q

Name 5 types of shapes/geometries of molecules.

A
2 - Linear
1 + 3 - trigonal planar
1 + 4 - tetrahedral
1 + 5 - trigonal bypyramidal
1 + 6 - octahedral
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2
Q

What is the bond angle of linear molecule?

A

180 degrees

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3
Q

What is the bond angle of trigonal planar molecule?

A

120 degrees

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4
Q

What is the bond angle of tetrahedral molecule?

A

109.5 degrees

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5
Q

What is the bond angle of trigonal bipyramidal molecule between equatorial atoms?

A

120 degrees

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6
Q

What is the bond angle of octahedral molecule?

A

90 degrees

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7
Q

What is the bond angle of trigonal bipyramidal molecule between axial to equatorial atoms?

A

90 degrees

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8
Q
Arrange the Strength of Repulsive Forces in decreasing order:
LP-BP
LP-BP
BP-BP
(LP: Lone pair, BP: Bond pair)
A

LP-LP > LP-BP > BP-BP

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9
Q

What 2 factors affect bond angles?

  1. ____ (2 words)
  2. ____ (2 words)
A

Lone pairs, Bond order

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10
Q

To determine overall dipole of a molecule,

  1. For dipoles opposite one another, ____.
  2. For dipoles at different orientation, take ____ (2 words).
A

Cancel, Vector sum

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11
Q

Molecule is polar when bond dipoles do not ____ and it contains ____ bonds.

A

Cancel, Polar

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12
Q

Molecular polarity is affected by ____ and ____ (2 words).

A

Shape, Bond polarity

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13
Q

____ are sets of molecules with same chemical formula but different structures.

A

Isomers

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14
Q

____ (2 words) occurs when pairs of molecules exists as ____ (2 words) mirror images.

A

Optical isomerism, Non-superimposable

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15
Q

Paired optical isomers have same ____ properties but different ____ properties.

A

Physical, Chemical

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16
Q

____ center has ____ carbon atom.

A

Chiral, Asymmetric

17
Q

____ carbon has ____ different atoms/groups arranged tetrahedrally around it.

A

Asymmetric, Four