7. electricity and chemical change Flashcards
conduction
- only solids that conduct are metals and carbon (graphite)
2.molecular substances are non-conductors - ionic compounds don’t conduct when solid but conduct when melted or dissolved in water
electrolysis
decomposition of an ionic compound when molten or in aqueous solution by the passage of an electric current
positive electrode
anode
negative electrode
cathode
during electrolysis
positive ions go to negative electrode so anion to anode
negative ions go to positive electrode so cations to cathode
why does decomposition occur
1 electrons flow along wire from negative terminal of the battery to the cathode
2 in liquid the ions carry the current and move to electrode of opposite charge
3 at cathode, cations accept electrons
4 at anode, anions give up electrons
5 electrons flow along the wire from anode to the positive terminal of the battery
rules for electrolysis of a solution: CATHODE
metal or hydrogen forms
-more the reactive an element the more it likes to stay as ions so if a metal is more reactive than hydrogen, it stays as ions and hydrogen bubbles off
-if metal is less reactive than metal forms
rules for electrolysis of a solution: ANODE
a non-metal other than hydrogen forms
-if its a concentrated solution of a halide (Cl-,Br-,I-) then chlorine, bromine or iodine form
-if the halide solution is dilute or there is no halide then oxygen forms
RAC
reduction at cathode so gain of electrons at cathode
Half equation for electrode reactions
1 name the ions present and the products
2. write each half equation correctly (positive ion at cathode, negative at anode)
3, add state symbols
electroplating
using electricity to coat one metal with another
cathode - obj to be electroplated
anode - metal X
electrolyte - a solution of a soluble compound of X