6.3 photochemical smog Flashcards

1
Q

primary pollutants

A
  • pollutants directly emitted from their source
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2
Q

secondary pollutants

A
  • primary pollutants react in the atmosphere and form secondary pollutants
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3
Q

secondary pollutants

A

acid rain
- nitrogen oxide and sulphur dioxide with water
ozone
- nitrogen dioxide and hydrocarbons with UV

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4
Q

impacts of primary pollutants

A

carbon dioxide and water vapour
- GHGs, increase average global temperature

sulphur dioxide
- respiratory and eye irritant
- component of acid rain

nitrogen oxides (NOx)
- reduces visibility
- respiratory irritant
- component of acid rain
- precursor of photochemical smog and formation of ozone

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5
Q

formation of photochemical smog

A
  • sunlight activates reactions between nitrogen oxides (NOx) and volatile organic compounds (VOCs), forming ozone and peroxyacyl nitrates (PAN).
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6
Q

factors influencing production of photochemical smog

A
  • amount of industry
  • population size
  • mode of transport used in an area
  • high levels of sunlight, more ozone during sunniest part of day
  • calm or light winds, reduces dispersion and dilution, pollutants contaminate at ground level
  • dry weather, doesnโ€™t wash pollutants out of air
  • topography, pollutants accumulate in valley, reduce air flow, tall buildings
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7
Q

thermal inversion layer

A
  • normally air at ground level warms and rises, dissipating pollutants
  • air expands and cools, temperature gradient

-thermal inversion, cold air trapped below a warm layer of air, only lasts a few hours
- windless condition, pollutants accumulate at ground level

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8
Q

impact of tropospheric ozone

A
  • highly reactive
  • inflammation of lungs coughing, lung disease
  • irritates eyes and nose
  • damages cells in leaves disrupting photosynthesis
  • damages fabrics, rubber and plastic
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9
Q

case study
LA smog

A
  • thermal inversion, valley of LA
  • high pollution, sunlight, low winds, not dispersed
  • photochemical smog
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10
Q

reduce air pollution
changing human behaviour

A
  • educational campaigns
  • individual change, energy efficient devices, turning off when not in use, reduce loss of heat in homes, decrease consumption of nonessential goods, decrease individual car use, hybrid or electric cars
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11
Q

reduce air pollution
economic instruments

A
  • pollution tax, increased for more released
  • subsidies for new technology and research
  • tax credits, subsidies for using renewable energy sources
  • subsidising public transport
  • road tolls and parking charges, discourage car use
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12
Q

reduce air pollution
technological changes

A

catalytic converters
- on motor vehicles
- oxidises carbon monoxide and VOCs
- reduces NOxs

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13
Q

reduce air pollution
+

A
  • increase energy efficiency
  • alternative energy sources
  • continuing research, low emission transport, renewable energy, efficiency of current products
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14
Q

reduce air pollution
legislation

A
  • set stricter emission standards
  • building regulations, efficiency of new and existing buildings, reduce heat loss, more efficient appliances
  • planning regulations, place power stations areas least likely to allow air pollution to accumulate
  • promote alternatives for private car use
  • clean up measures and restoration, scrubbers to clean discharge
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15
Q

case study
beijing

A
  • conditions favourable for the formation of photochemical smog
  • large population, high air emissions, poor city visibility

strategy to reduce air pollution
- replace coal burning power stations with gas
- limiting car use to alternative dates depending on license, some people 2 cars
- banning trucks and heavy emissions vehicles
- low number of new cars available for purchace

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16
Q

industrial smog

A
  • different than photochemical smog
  • caused by smoke and sulphur dioxide mixing with fog
17
Q

case study
london industrial smog

A
  • 1952, 4 days industrial smog
  • 4000 deaths, respiratory illness, lack of visibility
  • UK legislation cutting air pollution emissions, clean air act