[6.3] intermolecular forces Flashcards
where are intermolecular forces found?
- between molecules of simple covalent substances (eg. methane, water, iodine)
- not giant structures (eg. ionic, giant covalent, metallic)
what are the 3 types of intermolecular forces?
- london forces (weak)
- permanent dipole-dipole interactions (medium)
- hydrogen bonds (strong)
where are london forces found?
in all molecules (polar and non-polar)
what can london forces also be called?
- dispersion forces
- induced dipole-dipole interactions
describe how london forces arise [3]
- uneven distribution of electrons
- causes an instantaneous dipole
- causes induced dipoles in neighbouring molecules
what 2 factors affect the strength of a london force?
- the number of the electrons
- the shape of a molecule
how does the number of electrons affect the strength of a london force?
- the greater the number of electrons a molecule has, the stronger the instantaneous dipoles
- the greater the induced dipole-dipole interactions
- stronger attractive forces
how does the shape of a molecule affect the strength of a london force?
- the points of contain between molecules also affects the strength of the london forces
> straight chain molecules have greater points of contact so stronger london forces
> branched chain molecules have fewer points of contact so weaker london forces
where are permanent dipole-dipole interactions found?
in polar molecules only
what do simple molecules form in solid state?
in the solid state, simple molecules form a regular structure called a simple molecular lattice
what is the solubility of polar and non-polar substances?
- like dissolves like
> polar molecules will only dissolve in polar solvent
> non-polar substances will only dissolve in non-polar solvents
what is required for a solute to dissolve?
- the solute particles must be separated from each other and surrounded by the solvent particles
- the forces of attraction between solute and solvent particles must be strong enough to overcome the solute-solute and the solvent-solvent attractions
> non-polar substances cannot dissolve in polar solvents because the intermolecular forces cannot be broken