6.1.3 Melting Point Trend Flashcards

1
Q

Summary table of physical properties of period 3 oxides

A
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2
Q

What do Na2O and MgO form when reacted with water?

A
  • Purely ionic bonding
  • Alkaline solution
  • O2 becomes OH-
  • O2- (aq) + H2O (l) → 2OH- (aq)
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3
Q

What happens when P4O10 and SO2 and SO3 react with water?

A
  • Purely covalent
  • Acidic
  • Oxide + water forms acid which donate H+ to water
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4
Q

What happens when Al2O3 and SiO2 bond with water?

A
  • Insoluble
  • But with hot, concentrated alkaline solution, act as base and form a salt
  • Al can react with acidic solutions to form salt + water
  • Al exhibits amphoteric behavior, there is covalent character
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5
Q

Metal oxides with water

A
  • Form alkaline solutions
  • Sodium more because it is more soluble in water
  • O-2 ion is strong base and readily produces OH- ions when reacted with water
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6
Q

Oxides in middle of periodic table with water

A
  • Al2O3 has covalent character, ions held strongly in lattice despite being ionic
  • So does not dissolve
  • Si2O doesnt either
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7
Q

Non-metal oxides with water

A
  • P and S are simple covalent molecules
  • So react with water to produce acidic solutions
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8
Q

Oxides as acids and bases

A
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9
Q

Graphic trend in melting point of period 3 oxides

A
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10
Q

Why is the melting point of Al2O3 so high?

A
  • Ionic and has covalent character
  • So lots of energy required to overcome forces
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