6.1 Shapes of molecules and ions Flashcards
What is electron pair repulsion theory?
-Electron pairs repel as far as possible to produce the shape of a molecule
-Lone pairs repel more than bonding pairs, this can reduce bond angles
What does molecular shape depend on?
Electron pairs around the central atom
In what ways do electron pairs interact?
The repel each other as far as possible
What type of electron pair repel the most?
Lone pairs repel more than bonding pairs, reducing bond angles
What do dotted wedge, solid wedge and solid lines stand for?
Why does a lone pair repel more strongly than a bonded pair?
A lone pair of electrons is slightly closer to the central atom, and occupies more space than a bonded pair, resulting in lone pairs repelling more strongly
What is the order of pair repulsion, from strongest to weakest?
lone pair/lone pair
lone pair/bonding pair
bonding pair/bonding pair
What shape name is given to a molecule with no lone pairs but 4 bonded pairs?
Tetrahedral
What is the bond angle for a tetrahedral molecule?
109.5
What shape name is given to a molecule with 1 lone pairs and 3 bonded pairs?
Pyramidal
What is the bond angle in a pyramidal molecule?
107
What shape name is given to a molecule with 2 lone pairs and 2 bonded pairs?
Non-linear
What is an example of a tetrahedral molecule?
What is an example of a pyramidal molecule?
What is an example of a non-linear molecule
What shape name is given to a molecule with 0 lone pairs and 2 bonded pairs?
Linear
What is the bond angle of a linear shape?
180
What is an example of a linear molecule?
What shape name is given to a molecule with 0 lone pairs and 3 bonded pairs?
Trigonal planar
What is the bond angle in a trigonal planar molecule?
120
What is an example of a trigonal planar molecule?
What shape name is given to a molecule with 0 lone pairs and 5 bonded pairs?
Trigonal bipyramidal
What is the bond angle in a trigonal bipyramidal molecule?
There are actually two, 120 in one plane and 90 in the other plane
What shape name is given to a molecule with 0 lone pairs and 6 bonded pairs?
Octahedral
What is the bond angle of a octahedral molecule?
90
What happens to the bond angle as number of electron pairs increases?
Bond angle will decrease with more electron pairs