6 - Lasers Flashcards

1
Q

What properties do the stimulating and stimulated photons share?

A

Frequency/wavelength, direction of travel and phase.

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2
Q

What is population inversion?

A

The cascade movement of electrons from their excited state to the lower state resulting in the laser light emission.

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3
Q

What are the three components of a laser?

A

Active medium, Pump, Optical resonator.

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4
Q

What is an active medium?

A

A luminescent material which stores the excited population and can be stimulated to emit it in a cascade.

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5
Q

What is an pump?

A

The source of energy used to excite the molecules of the active medium.

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6
Q

What kinds of optical pump exist?

A

Optical pump - light such as a flash lamp that uses photon absorption to excite the active medium.

Electrical pump - energises the active medium through means such as electrical discharge.

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7
Q

What is an optical resonator?

A

The housing of the active medium which essentially comprises of two highly reflective mirrors at either end, one of which is partially non-reflecting.

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8
Q

Why must the length of the optical resonator/laser cavity be carefully controlled?

A

It must be an integer multiple of the wavelength to ensure that all waves stay in phase (coherence) so as not to cause destructive interference.

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9
Q

Which of the stimulated photons contribute to the lasing?

A

Those that propagate along the axis between the mirrors. Others are absorbed by the unmirrored surfaces.

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10
Q

What are the two kinds of laser?

A

3-level and 4-level.

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11
Q

Describe the sequence of events in a 3-level laser.

A

Optical pump irradiates the active medium with photons whose energy corresponds to an excitation to an unpopulated level.
Electrons partially relaxed non-radiatively to a slightly lower metastable state.
Spontaneous emission from the metastable state creates a cascade.

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12
Q

What is the main disadvantage of a 3-level laser?

A

The spontaneous and stimulated emission from the metastable state is to the ground state, hence the photons compete to be re-absorbed to re-populate the state. This makes them very inefficient.

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13
Q

What is the requirement for population inversion in a 3-level laser?

A

At least half the molecules in the active medium must be excited to the metastable state.

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14
Q

How do 4-level lasers solve the re-absorption competition problem?

A

The metastable state electron emits a photon to move down to an unstable state (second lasing level) that rapidly decays non-radiatively to the ground state, so the photons emitted are no longer the right energy for re-absorption.

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15
Q

Why is the metastable state stable?

A

Because the difference in energy between it and the first excited state mean that emission cannot be stimulated by the pumping.

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16
Q

What is different about the pumps that can be used in 4-level lasers?

A

They can be continuously pumped.

17
Q

What are the advantages of 4-level lasers?

A

Much easier to achieve and maintain population inversion, less pumping required.
Laser can be operated continuously as continuous pumping is possible.
Conversion efficiencies much higher.

18
Q

What is the advantage to using solute organic dyes as an active medium?

A

They possess many closely spaced vibrational energy levels in the lower lasing level, allowing the frequency to be very finely tuned using a diffraction grating.

19
Q

What special requirements are there for organic dye active mediums?

A

Effective stirring and cooling, as the second non-radiative relaxation generally produces heat by collision with the solvent.

20
Q

What range of frequencies are organic dye lasers largely limited to?

A

UV to IR

21
Q

What are the basic properties of laser light?

A

Highly monochromatic (esp w/ diffraction grating).
Coherent (ie same phase).
Highly parallel, so can be focused on a small area to produce huge local power density.

22
Q

What are pulsed lasers used for?

A

Ones such as ruby lasers are able to emit in 10^-15s pulses, allowing for femtosecond spectroscopy that can probe molecule’s bond vibration.