5.3 Transition Metals Flashcards
Define a transition metal
-d-block elements that have an ion with an incomplete d-sub shell
Why are scandium and zinc not classed as transition metals?
-because they do not have any ions with partially filled d-orbitals
-scandium only forms Sc+3 ion in which d-orbitals are empty
-zinc forms only Zn2+ ion in which d-orbitals are full
When writing electron configurations in what order should you write the 3d and 4s sub shell?
The 4s sub shell has a lower energy than the3d sub shell
This means that the 4s orbital fills before the orbitals in the 3D sub shell
What are the two transition metals do not follow the rules for filling sub shells?
Chromium-the five 3d-orbitals and the 4s orbital all contain one electron with no orbital being completely filled.
Copper-the five 3d-orbitals are full but there is only one electron in the 4s-orbital
Write out the electron configuration for chromium
1s2 2s2 2p6 3s2 3p6 4s1 3d5
Write out the electron configuration for copper
1s2 2s2 2p6 3s2 3p6 4s1 3d10
When forming positive ions from transition metals the ___ electrons are lost before the ____ electrons.
4s orbital
3d orbitals
As once the electrons occupy the orbitals the 4s electrons have a higher energy
(FIRST IN FIRST OUT)