5.3 - transition element colours Flashcards
Fe2+
green
Fe(OH)2
green pecipitate
Fe3+
yellow
Fe(OH)3
orange-brown precipitate
Cu
brown
Cu+
colourless
CuI
white precipitate
Cu2+
pale blue
[Cu(NH3)4(H20)2]2+
deep blue
Cu(OH)2
pale blue precipitate
[CuCl4]2-
yellow
Cr3+
violet
[Cr(NH3)6]3+
purple
Cr(OH)3
green precipitate
[Cr(OH)6]3-
green
Cr2O72-
orange
CrO42-
yellow
Mn2+
pale pink
Mn(OH)2
light brown
MnO4-
purple
[Cu(H2O)6]2+ + 4Cl- (reagent: conc HCl)
[CuCl4]2- +6H2O
[Cu(H2O)6]2+ + 4NH3 (reagent: excess NH3)
[Cu(NH3)4(H2O)2]2+ + 4H20
[Cr(H20)6]3+ + 6NH3 (reagent: excess NH3)
6H20 +[Cr(NH3)6]3+
notes on precipitation reactions:
Cu(OH)2
Redissolves in excess NH3 to give deep blue [Cu(NH3)4(H2O)2]2+
notes on precipitation reactions:
Cr(OH)3, excess NH3
purple [Cr(NH3)6]3+
notes on precipitation reactions:
Cr(OH)3, excess OH-
green [Cr(OH)6]3-