5.3- CATALYSTS Flashcards

1
Q

What are catalysts?

A

substances that affect rate of chemical reactions without being chemically changed themselves at end of reaction

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2
Q

What are catalysts usually used for?

A

used to speed up reactions so they’re important in industry

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3
Q

Why is it cheaper to use a catalyst than using high temps + pressures?

A

catalysts not used up

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4
Q

Why do catalysts work?

A

they provide different pathway for reaction, one with lower activation energy

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5
Q

What do catalysts reduce?

A

activation energy of reaction

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6
Q

Do catalysts affect the enthalpy change of a reaction?

A

no

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7
Q

Do catalysts affect the position of equilibrium in a reversible reaction?

A

no

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8
Q

What are all new petrol-engine cars now equipped with?

A

catalytic converters in their exhaust systems

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9
Q

What do catalytic converters in the exhaust systems of petrol-engine cars do?

A

reduce levels of number of polluting gases

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10
Q

What is the catalytic converter?

A

honeycomb, made of ceramic material coated with platinum + rhodium metals- catalysts

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11
Q

What does the honeycomb shape of catalytic converters provide?

A

enormous SA, on which reactions take place, so little of these expensive metals goes a long way

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12
Q

Reactions for the polluting gases forming less harmful products from catalytic converters? (2)

A

carbon monoxide + nitrogen oxides -> nitrogen + carbon dioxide

hydrocarbons + nitrogen oxides -> nitrogen + carbon dioxide + water

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13
Q

Where does the reactions for the catalytic converter happen?

A

on surface of catalyst

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14
Q

What is the first process for the catalytic convert reactions?

A

adsorption

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15
Q

What is adsorption (first step of catalytic convert reactions)?

A

gases first form weak bonds with metal atoms of catalyst

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16
Q

What does adsorption do? (first step of catalytic convert reactions)

A

holds gases in just the right position for them to react together
gases then react on surface

17
Q

What is the second process for catalytic convert reactions?

A

desorption

18
Q

What is desorption? (second step of catalytic convert reactions)

A

products then break from metal atoms

19
Q

What does desorption do? (second step of catalytic convert reactions)

A

frees up room on catalyst surface for more gases to take their place + react

20
Q

Why is the strength of the weak bonds holding the gases onto the metal surface of the catalytic converter critical?

A

must be strong enough to hold gases for long enough to react, but weak enough to release products easily