5.2 redox chemistry 🐂 Flashcards
what is disproportionation reaction?
a reaction in which the same element is simultaneously reduced and oxidised to form two different products
what is comproportionation reaction?
a reaction in which the two reactants, each containing the same element but with different oxidation state, will form a product in which the element involved reaches the same oxidation state
whats the #1 rule in redox!!
amount of electrons lost from oxidation = amount of electrons gained in reduction
common oxidising agents (reduced)
- Mn O4- -> Mn2+ (acidic)
- MnO4- -> MnO2 (basic)
- Cr2O7 2- -> Cr3+ (acidic)
- Fe3+ -> Fe2+
- I2 -> 2I-
- SO4 2- -> SO3 2-
- H2O2 -> H2O
common reducing agents (oxidised)
- Fe2+ -> Fe3+
- 2I- -> I2
- H2O2 -> O2
- SO3 2- -> SO4 2-
why is H2SO4 used to provide acidic medium and not HCl and HNO3?
HCl is not used as the chloride ions will get oxidised by MnO4-.
HNO3 is not used as it is a strong oxidising agent and will interfere with oxidising action of MnO4-