5.1.2 - How far Flashcards
Calculating Kc
ICEE table Inital moles Change in mol Equilbrium mol Eqm conc (eqm mol/ vol.)
Units of conc
moldm^-3
Kp
Kc for gases
(pC)^c * (pD)^d / (pA)^a * (pB)^b
Mole fraction
Number of moles in A/ total no. of moles
Partial pressure
Mole fraction * total pressure
Kp in heterogenous equilibria
Do not include solids or liquids in final Kp expression
Explain in terms of Kc what happens to the eqm if temp is increased/ decreased
If reaction is exo/endo increase/decrease in temp shifts the eqm to lhs/rhs
As a result there will be more … which increases the denominator/numerator of the Kc expression
Kc will decrease/ increase
Explain what happens in terms of Kc to the eqm if conc is changed
Kc doesn’t change, only changes w/ temp
Increasing the conc of … increases the numerator/denominator of the Kc exp.
The eqm. shifts towards the left/right so more – will be made to restore eqm
Explain what happens in terms of Kc to the eqm if pressure changes
Kp doesn’t change only changes with temp
increasing pressure, increases all conc.n
The d/n will increase more than the n/d
The eqm shifts to the left/ right and makes more … to restore the eqm
Is the dissociation of water (Kw) exo/endo
Endo as the value of Kw increases with temp
Units of kP
atm or kPa