5.1 Flashcards

1
Q

Thermochemistry

A

the study of the energy
changes that accompany physical or chemical
changes in matter

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2
Q

Energy

A

the ability to do work

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3
Q

Work

A

the amount of energy transferred by a
force over a distance

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4
Q

Potential Energy

A

the energy of a body or
system due to its position or composition

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5
Q

Kinetic Energy

A

the energy of an object due
to its MOTION

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6
Q

the energy associated with chemical bonds is

A

potential energy

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7
Q

Thermal Energy

A

total quantity of kinetic and
potential energy in a substance

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8
Q

thermal energy depends on…

A

how fast entities in a substance are moving

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9
Q

heat

A

transfer of thermal energy from a warm object to a cooler object

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10
Q

“cold” is simply…

A

the absence of heat

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11
Q

Temperature

A

average kinetic energy of
entities in a substance

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12
Q

Law of Conservation of Energy

A

energy cannot be created or
destroyed

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13
Q

Chemical system

A

a group of reactants and products being studied

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14
Q

Surroundings

A

all matter that is not part of the system

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15
Q

Open System

A

both matter and energy are free to enter and leave the system

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16
Q

Closed System

A

energy can enter and leave the system, but not matter

17
Q

isolated system

A

neither matter nor energy can move into or out of the system

18
Q

exothermic reaction

A

Chemical reaction that releases energy to the
surroundings

19
Q

for an exothermic reaction, products have ______ PE than the reactants

A

lower

20
Q

for an exothermic reaction, temperature of the surroundings will ________

A

increase

21
Q

endothermic reaction

A

chemical reaction which absorbs energy
from the surroundings

22
Q

for an endothermic reaction, products have ______ PE than the reactants

A

higher

23
Q

are nuclear reactions all exothermic or endothermic?

A

exothermic

24
Q

what are the 2 nuclear reactions that involve large quantities of energy

A

fusion and fission

25
Q

what is fusion

A

the process of combining two or more
nuclei of low atomic mass to form a heavier, and
more stable nucleus

26
Q

what is fission

A

the process of using a neutron to split a
nucleus of high atomic mass into two nuclei with
smaller masses

27
Q

specific heat capacity

A

the quantity of
thermal energy required to raise the temperature
of 1 g of a substance by 1 degree celcius

28
Q

Calorimetry

A

the process of measuring thermal energy changes during a
physical or chemical change

29
Q

what must a calorimeter contain

A

a well-insulated reaction chamber at constant pressure, a tight-fitting cover with insulated holes for a thermometer, and a stirrer

30
Q

in a calorimeter, any change in the thermal energy of the system is detected as a ________

A

temperature change

31
Q

what calorimeter is used for gases?

A

a bomb calorimeter

32
Q

enthalpy

A

total amount of thermal energy in a substance

33
Q

how is enthalpy measured

A

cannot be measured but can be calculated using calorimetry data

34
Q

enthalpy change

A

the energy released to or absorbed from the surroundings during a chemical or physical change

35
Q

as long as pressure remains constant, delta h =

A

q system

36
Q

molar enthalpy change

A

the enthalpy change associated with a physical,
chemical or nuclear change involving 1 mol of a
substance

37
Q

For molar enthalpy change of formation of a
product, the coefficient in the equation must
always ___

A

1

38
Q

thermochemical equation

A

a chemical equation that describes the enthalpy change of a reaction

39
Q
A