5 ENTHALPY CHANGE Flashcards
Standard enthalpy change of reaction
The enthalpy change when molar quantities of reactants as specified by the chemical equation react to form products at 1 bar and 298 K
Standard enthalpy change of formation
The enthalpy change when 1 mole of a substance is formed from its constituent elements in their standard states at 298 K and 1 bar.
Standard enthalpy change of combustion
energy released when 1 mole of a substance is completely burnt in excess oxygen at 298 K and 1 bar.
Standard enthalpy change of neutralisation
energy released when 1 mole of water is formed in the neutralisation reaction between an acid and a base, at 298 K and 1 bar.
Standard enthalpy change of atomisation (for elements)
energy required to form 1 mole of gaseous atoms from the element at 298 K and 1 bar.
Standard enthalpy change of atomisation
for compounds
energy required to form gaseous atoms from 1 mole of the compound at 298 K and 1 bar.
Bond Energy B.E.
The average energy required to break 1 mole of a covalent bond in the gaseous state
1st Ionisation Energy
energy required to remove 1 mole of e from 1 mole of gaseous atoms to form 1 mole of singly charged gaseous cations
1st Electron Affinity
enthalpy change when 1 mole of e is added to 1 mole of gaseous atoms to form 1 mole of singly charged gaseous anions.
Lattice Energy
energy released when 1 mole of solid ionic compound is formed from constituent gaseous ions
Standard enthalpy change of hydration
energy released when 1 mole of gaseous ions is dissolved in an infinite volume of water at 298 K and 1 bar.
Standard enthalpy change of solution
enthalpy change when 1 mole of solute is completely dissolved in an infinite volume of solvent at 298 K and 1 bar.