5. Electrons and Bonding Flashcards

1
Q

What is the electron configuration of Chromium, Cr?

A

1s2, 2s2, 2p6, 3s2, 3p6, 4s1, 3d5

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2
Q

What is the electron configuration of Copper, Cu?

A

1s2, 2s2, 2p6, 3s2, 3p6, 4s1, 3d10

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3
Q

Which shell fills first? 4s or 3d?

A

4s fills and empties before 3d

4s is a lower energy shell so fills first

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4
Q

How do electrons pair?

A

with opposite spin

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5
Q

How to you draw electrons in an energy level diagram?

A

1 arrow pointing up, 1 pointing down

fill all boxes singly first then come back and pair

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6
Q

What does it mean if something is in the s block?

A

its highest energy electrons are in the s sub-shell

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7
Q

What are the properties of ionic compounds?

A

high melting + boiling points
tend to dissolve in water + polar solvents
conduct electricity only as a liquid or solution

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8
Q

Which energy shells fill first?

A

lower energy shells

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9
Q

Define an ionic bond

A

the electrostatic attraction between oppositely charged ions

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10
Q

Define a covalent bond

A

the electrostatic attraction between the negatively charged bonding pair of electrons and the positive nuclei of the atoms involved

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11
Q

In which directions do ions attract each other? What does this mean for ionic compounds?

A

attract in all directions and 3 dimensions

allows a giant lattice structure containing billions of molecules to form

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12
Q

Where is the attraction in a covalent bond?

A

it is localised

solely between the shared pair and the nuclei

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13
Q

Define a double/triple covalent bond

A

the electrostatic attraction between the 2/3 shared pairs of electrons and the nuclei of the atoms involved

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14
Q

Define a dative (coordinate) covalent bond

A

a covalent bond in which the shared pair of electrons has been supplied by 1 of the bonding atoms only

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15
Q

What was a dative bond before it became a bond?

A

a lone pair

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16
Q

How do you show a dative bond on a dot cross diagram?

A

an arrow going from the donating atom to the receiving atom

17
Q

What is average bond enthalpy?

A

a measure of covalent bond strength

18
Q

How many electrons are there in the fourth shell?

A

32
(2 in s shell, 6 in p shell, 10 in d shell and 14 in f shell)
(2n^2)

19
Q

How many p orbitals from each shell in n=2 contain?

A

3

therefore 6 electrons

20
Q

How many d/f orbitals from each shell in n=3/4 contain?

A

5 and 7

therefore 10 and 14 electrons