5) Acids and bases Flashcards
D) Arrhenious theory
Acids: produce H+ ions
Bases: produce OH- ions
D) Lowry-bronsted theory
Acid: proton donor
Base: proton acceptor
D) Lewis theory
Acid: contains vacant orbital
Base: contains lone pair
D) Strong acids
Ionise completely.
HClO4
HCl
H2SO4
HNO3
D) Strong bases
Dissociate completely,
NH2-
O2-
H-
E) Molar expansion of water
Kw = [H3O+][OH-]
= 1 x 10-14
E) pH and pOH
pH = -log [H+]
pOH = -log [OH-]
pH + pOH = 14
E) % ionisation
= [H+] at equilibrium / [H+] initially x 100
E) Ka and Kb
Ka = [H+][A-]/[HA]
Kb = [OH-][BH+]/[B]
Kw = Ka x Kb
E) pH for buffers
pH = pKa + log( [conj base] / [acid])
E) Salts
Salt = strong acid + strong base ion
D) Buffers
Weak acid + its conj base
Weak base + its conj acid