422 practice Flashcards
1
Q
R2XCuLi
A
Adds R to group at meta position
2
Q
H3O+ and heat
A
Cuts off ketone
3
Q
What parts of molecules do condensation reactions react with?
A
Partial positive and 2H
4
Q
H3O+ and heat with an aldol
A
Cut aldol in half, sub EtO for OH
5
Q
What’s a good LG for a grignard?
A
OMe
6
Q
Grignard bases turn OH to
A
O-
7
Q
NaBH4 is _______ agent
A
Reducing
8
Q
How do you determine the grignard reagent?
A
Remove Ketone
9
Q
- PBr3
- Mg
A
Subs OH for MgBr, which leaves on its own
10
Q
NaCN
A
LP on C attacks carbon, stays there.
11
Q
Williamson ether
A
Alkoxide substitutes halide
12
Q
Opening rings is a _______ mechanism, which means ___________
A
SN2, attacked from the back
13
Q
Acids _________ alkyls
A
Cleave more subtituted
14
Q
2 adjacent functional groups-
A
Former epozide. (Carbon connected to the nucleophile is where it was cut.
