4.2 Chemical Bonding and Structure Flashcards
What does ionic bonding involve?
Ionic bonds involve the transfer of electrons from a metallic element to a non-metallic element
Why do elements want to have full outer shells?
Transferring electrons usually leaves the metal and the non-metal with a full outer shell
What electron arrangement do atoms have when they form ions?
Once the atoms become ions, their electronic configurations are the same as a noble gas
What type of forces are in ionic lattices?
Cations and anions are oppositely charged and therefore attracted to each other
Electrostatic attractions are formed between the oppositely charged ions to form ionic compounds
Why do ionic compounds have high mp and bp?
This form of attraction (electrostatic forces) is very strong and requires a lot of energy to overcome
This causes high melting points in ionic compounds
What structures do ionic lattices form?
The ions form a lattice structure which is an evenly distributed crystalline structure
How are ions arranged in a lattice?
Ions in a lattice are arranged in a regular repeating pattern so that positive charges cancel out negative charges
What charge does the lattice have?
Therefore the final lattice is overall electrically neutral
What affects the melting/boiling point of a substance?
Different types of structure and bonding have different effects on the physical properties of substances such as their melting and boiling points, electrical conductivity and solubility
Are ionic compounds weak/strong? Why?
Ionic compounds are strong
The strong electrostatic forces in ionic compounds keep the ions strongly together
Are ionic compounds brittle/malleable?
They are brittle as ionic crystals can split apart
What increases the melting and boiling points of ionic compounds?
The strong electrostatic forces between the ions in the lattice act in all directions and keep them strongly together
Melting and boiling points increase with charge density of the ions due to the greater electrostatic attraction of charges
Mg2+O2- has a higher melting point than Na+Cl–
Are ionic compounds in/soluble in water?
Ionic compounds are soluble in water as they can form ion – dipole bonds
Can ionic compounds conduct electricty?
Ionic compounds only conduct electricity when molten or in solution
Why can ionic compounds only conduct electricity in molten state?
When molten or in solution, the ions can freely move around and conduct electricity
Why do ionic compounds not conduct electricity when solid?
In the solid-state they’re in a fixed position and unable to move around
What elements form an ionic compound?
Ionic compounds are formed from a metal and a nonmetal bonded together
What elements does covalent bonding occur between?
Covalent bonding occurs between two non-metals
What forces are in a covalent bond?
A covalent bond involves the electrostatic attraction between nuclei of two atoms and the electrons of their outer shells
How do the atoms achieve full outer shells in ionic bonding?
No electrons are transferred but only shared in this type of bonding
What is formed during a covalent bond?
When a covalent bond is formed, two atomic orbitals overlap and a molecular orbital is formed
Why does covalent bonding occur?
Covalent bonding happens because the electrons are more stable when attracted to two nuclei than when attracted to only one
How should the electrons in a covalent bond be regarded as?
Covalent bonds should not be regarded as shared electron pairs in a fixed position; the electrons are in a state of constant motion and are best regarded as charge clouds
Will the central atom always have an octet?
NO
Covalent bonds should not be regarded as shared electron pairs in a fixed position; the electrons are in a state of constant motion and are best regarded as charge clouds